(2S,4S)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine

Base Information

Chemical Name:(2S,4S)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine
CAS No.:1176196-33-0
Molecular Formula:C₂₄H₂₆N₂
Molecular Weight:342.484
Hs Code.:

Synonyms:(2S,4S)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine

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Chemical Property of (2S,4S)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine

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Technology Process of (2S,4S)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine

There total 2 articles about (2S,4S)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 89586-95-8
2-methyl-2,4-di(4-methylphenyl)-2,3-dihydro-1H-1,5-benzodiazepine

: C₂₄H₂₆N₂

: 1176196-33-0
(2S,4S)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine

: 1176196-10-3
(2S,4R)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine

Guidance literature:: With C₁₂H₁₀O₄P^(1-)*C₂₅H₃₁N₂O₂RuS⁽¹⁺⁾; hydrogen; In dichloromethane; at 40 ℃; for 10h; under 38002.6 Torr; stereoselective reaction; Autoclave; Glovebox;
DOI:10.1002/ejoc.201700236

Reference yield:

: 89586-95-8
2-methyl-2,4-di(4-methylphenyl)-2,3-dihydro-1H-1,5-benzodiazepine

: C₂₄H₂₆N₂

: C₂₄H₂₆N₂

: 1176196-33-0
(2S,4S)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine

: 1176196-10-3
(2S,4R)-2-methyl-2,4-di-p-tolyl-2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine

Guidance literature:: With 4-hydroxy-2,6-diphenyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide; diallyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; sodium sulfate; In chloroform; at -10 ℃; for 132h; optical yield given as %ee; enantioselective reaction;
DOI:10.1016/j.bmcl.2009.05.039