silver(I) pentafluorobenzenethiolate

Base Information

• Chemical Name: silver(I) pentafluorobenzenethiolate
• CAS No.: 18695-30-2
• Molecular Formula: Ag*C₆F₅S
• Molecular Weight: 306.992
• Mol file: 18695-30-2.mol

Synonyms:silver(I) pentafluorobenzenethiolate

Chemical Property of silver(I) pentafluorobenzenethiolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of silver(I) pentafluorobenzenethiolate

There total 9 articles about silver(I) pentafluorobenzenethiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.3%

silver(I) 2-pyrrolidone-5-carboxylate + pentafluorophenylthiol (771-62-0) → silver(I) pentafluorobenzenethiolate (18695-30-2)

Guidance literature:

In ethanol; water; byproducts: R,S-2-pyrrolidone-5-carboxylic acid; org. compd. added to soln. of Ag compd. in 1:1 H2O-EtOH (v/v), stirred for 1 h; filtered, washed with water, EtOH and ether, dried in vac. for 2 h; elem. anal.;

DOI:10.1016/j.inoche.2005.10.003

Reference yield: 91.2%

pentafluorophenylthiol (771-62-0) + silver nitrate → silver(I) pentafluorobenzenethiolate (18695-30-2)

Guidance literature:

With aq. NaOH; In ethanol; water; org. compd. added to soln. of Ag compd. in 1:1 H2O-EtOH (v/v), calc. amt. of aq. NaOH added, stirred for 1 h; filtered, washed with water, EtOH and ether, dried in vac. for 2 h, product contaminated with NO3(1-) ion;

DOI:10.1016/j.inoche.2005.10.003

Reference yield: 86.0%

[Au2(SC6F5)2(μ-1,1'-bis(diphenylphosphino)ferrocene)] (244028-98-6) + silver perchlorate → [Au2(μ-SC6F5)(μ-1,1'-bis(diphenylphosphino)ferrocene)]ClO4 (244029-21-8) + silver(I) pentafluorobenzenethiolate (18695-30-2)

Guidance literature:

In dichloromethane; equiv. amts.; stirring (1 h, in dark); filtration of Ag-polymer, filtrate concg., pptn. on Et2O addn.; elem. anal.;

DOI:10.1021/om9901372

upstream raw materials:

pentafluorophenylthiol

[Au2(SC6F5)2(μ-1,1'-bis(diphenylphosphino)ferrocene)]

silver(l) oxide

Hexafluorobenzene

Downstream raw materials:

silver

Pentafluorphenylthioacetat

Pentafluorphenylthio-trimethyl-silan