C₄₉H₆₀O₉SiC₉H₂₀

Base Information

Chemical Name:C₄₉H₆₀O₉SiC₉H₂₀
CAS No.:944823-57-8
Molecular Formula:C₅₈H₈₀O₉Si
Molecular Weight:949.353
Hs Code.:

C<sub>49</sub>H<sub>60</sub>O<sub>9</sub>SiC<sub>9</sub>H<sub>20</sub>

Synonyms:C₄₉H₆₀O₉SiC₉H₂₀

Suppliers and Price of C₄₉H₆₀O₉SiC₉H₂₀

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₄₉H₆₀O₉SiC₉H₂₀

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₄₉H₆₀O₉SiC₉H₂₀

There total 31 articles about C₄₉H₆₀O₉SiC₉H₂₀ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 938455-50-6
C₄₉H₆₀O₉

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 944823-57-8
C₄₉H₆₀O₉SiC₉H₂₀

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 2.5h;
DOI:10.1016/j.tet.2007.02.039

Reference yield:

: 100-39-0
benzyl bromide

: 944823-57-8
C₄₉H₆₀O₉SiC₉H₂₀

Guidance literature:: Multi-step reaction with 18 steps

1.1: NaH / dimethylformamide / 1.5 h / 0 °C

1.2: Bu₄NI / dimethylformamide / 15 h / 20 °C

2.1: 3.95 g / p-TsOH*H₂O / methanol / 3 h / 40 - 70 °C

3.1: 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

4.1: 4.77 g / CSA / CH₂Cl₂; methanol / 2 h / 0 °C

5.1: 94 percent / Et₃N; SO₃*pyridine / CH₂Cl₂; dimethylsulfoxide / 2.5 h / 20 °C / Parikh-Doering oxidation

6.1: t-BuLi; HMPA / tetrahydrofuran; pentane / 0.33 h / -78 °C

6.2: 95 percent / tetrahydrofuran; pentane / 1.5 h / -78 °C

7.1: 93 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - 20 °C

8.1: 98 percent / methanol; tetrahydrofuran / 11 h / 20 °C

9.1: 93 percent / HF*pyridine; pyridine / tetrahydrofuran / 15 h / 20 °C

10.1: 87 percent / pyridinium p-toluenesulfonate / toluene / 3.5 h / 100 °C

11.1: 92 percent / DIBALH / toluene / 2 h / -78 °C

12.1: BH₃*THF / tetrahydrofuran / 3 h / 0 - 20 °C

12.2: 91 percent / aq. NaOH; H₂O₂ / tetrahydrofuran / 3.5 h / 20 °C

13.1: 5.13 g / 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

14.1: DDQ; phosphate buffer / CH₂Cl₂ / 1 h / 0 °C / pH 7

15.1: tetra-n-propylammonium perruthenate; NMO; molecular sieves 4 Angstroem / CH₂Cl₂ / 6.08 h / 0 - 20 °C

16.1: 2.89 g / TBAF; acetic acid / tetrahydrofuran / 7.5 h / 20 °C

17.1: 83 percent / TMSOTf; Et₃SiH / acetonitrile / 0.25 h / -10 °C

18.1: 3.14 g / 2,6-lutidine / CH₂Cl₂ / 2.5 h / 20 °C

With pyridine; 2,6-dimethylpyridine; triethylsilane; N,N,N,N,N,N-hexamethylphosphoric triamide; N-methyl-2-indolinone; phosphate buffer; tetrapropylammonium perruthennate; borane-THF; oxalyl dichloride; pyridine-SO₃ complex; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; tert.-butyl lithium; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; pyridine hydrogenfluoride; acetic acid; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; acetonitrile; pentane; 7.1: Swern oxidation;
DOI:10.1016/j.tet.2007.02.039

Reference yield:

: 938455-96-0
C₂₅H₃₂O₅

: 944823-57-8
C₄₉H₆₀O₉SiC₉H₂₀

Guidance literature:: Multi-step reaction with 18 steps

1.1: NaH / dimethylformamide / 1.5 h / 0 °C

1.2: Bu₄NI / dimethylformamide / 15 h / 20 °C

2.1: 3.95 g / p-TsOH*H₂O / methanol / 3 h / 40 - 70 °C

3.1: 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

4.1: 4.77 g / CSA / CH₂Cl₂; methanol / 2 h / 0 °C

5.1: 94 percent / Et₃N; SO₃*pyridine / CH₂Cl₂; dimethylsulfoxide / 2.5 h / 20 °C / Parikh-Doering oxidation

6.1: t-BuLi; HMPA / tetrahydrofuran; pentane / 0.33 h / -78 °C

6.2: 95 percent / tetrahydrofuran; pentane / 1.5 h / -78 °C

7.1: 93 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - 20 °C

8.1: 98 percent / methanol; tetrahydrofuran / 11 h / 20 °C

9.1: 93 percent / HF*pyridine; pyridine / tetrahydrofuran / 15 h / 20 °C

10.1: 87 percent / pyridinium p-toluenesulfonate / toluene / 3.5 h / 100 °C

11.1: 92 percent / DIBALH / toluene / 2 h / -78 °C

12.1: BH₃*THF / tetrahydrofuran / 3 h / 0 - 20 °C

12.2: 91 percent / aq. NaOH; H₂O₂ / tetrahydrofuran / 3.5 h / 20 °C

13.1: 5.13 g / 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

14.1: DDQ; phosphate buffer / CH₂Cl₂ / 1 h / 0 °C / pH 7

15.1: tetra-n-propylammonium perruthenate; NMO; molecular sieves 4 Angstroem / CH₂Cl₂ / 6.08 h / 0 - 20 °C

16.1: 2.89 g / TBAF; acetic acid / tetrahydrofuran / 7.5 h / 20 °C

17.1: 83 percent / TMSOTf; Et₃SiH / acetonitrile / 0.25 h / -10 °C

18.1: 3.14 g / 2,6-lutidine / CH₂Cl₂ / 2.5 h / 20 °C

With pyridine; 2,6-dimethylpyridine; triethylsilane; N,N,N,N,N,N-hexamethylphosphoric triamide; N-methyl-2-indolinone; phosphate buffer; tetrapropylammonium perruthennate; borane-THF; oxalyl dichloride; pyridine-SO₃ complex; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; tert.-butyl lithium; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; pyridine hydrogenfluoride; acetic acid; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; acetonitrile; pentane; 7.1: Swern oxidation;
DOI:10.1016/j.tet.2007.02.039