1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose

Base Information

Chemical Name:1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose
CAS No.:97292-02-9
Molecular Formula:C₂₁H₂₁F₃O₇S
Molecular Weight:474.455
Hs Code.:

Synonyms:1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose

Suppliers and Price of 1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose

There total 13 articles about 1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 358-23-6
trifluoromethylsulfonic anhydride

: 67227-89-8
1,6-anhydro-3,4-di-O-benzyl-β-D-mannopyranoside

: 97292-02-9
1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose

Guidance literature:: With pyridine; In dichloromethane; at 0 ℃; for 2h;
DOI:10.1021/jo00267a022

Reference yield:

: 20888-02-2
1,6-anhydro-2,3,4-tri-O-benzyl-β-D-mannopyranose

: 97292-02-9
1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / SnCl₄ / CH₂Cl₂ / 0.5 h / Ambient temperature; var. Lewis Acids, var. 1,6-anhydrohexapyranose derivatives or perbenzyl ether of glycol

2: pyridine / CH₂Cl₂ / 2 h / 0 °C

With pyridine; tin(IV) chloride; In dichloromethane;
DOI:10.1021/jo00267a022

Reference yield:

: 100-39-0
benzyl bromide

: 97292-02-9
1,6-anhydro-3,4-di-O-benzyl-2-O-<(trifluoromethyl)sulfonyl>-β-D-mannopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaH / 1.) DMF, 0 deg C, 2 h, 2.) DMF, RT, 2 d

2: 89 percent / molecular sieves 4A, trimethylamine-borane, AlCl₃ / tetrahydrofuran / 5 h / Ambient temperature

3: pyridine / CH₂Cl₂

With pyridine; aluminium trichloride; 4 A molecular sieve; trimethylamine borane; sodium hydride; In tetrahydrofuran; dichloromethane;
DOI:10.1246/bcsj.67.1756