N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide

Base Information

• Chemical Name: N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide
• CAS No.: 165550-61-8
• Molecular Formula: C₃₄H₂₇NO₂
• Molecular Weight: 481.594
• Mol file: 165550-61-8.mol

Synonyms:N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide

Chemical Property of N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide

There total 3 articles about N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

N-(2,6-diisopropylphenyl)-4,5-dibromonaphthalene-1,8-dicarboximide (1246857-77-1) + 1-naphthylboronic acid pinacol ester (68716-52-9) → N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide (165550-61-8)

Guidance literature:

N-(2,6-diisopropylphenyl)-4,5-dibromonaphthalene-1,8-dicarboximide; 1-naphthylboronic acid pinacol ester; With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; caesium carbonate; tricyclohexylphosphine tetrafluoroborate; at 20 ℃; Schlenk technique; Inert atmosphere;

at 160 ℃; for 16h; Reagent/catalyst;

DOI:10.1021/acs.joc.8b00301

Reference yield: 65.0%

2,6-diisopropylbenzenamine (24544-04-5) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide (165550-61-8)

Guidance literature:

With 1H-imidazole; zinc(II) acetate dihydrate; In water; at 190 ℃; for 24h; Autoclave;

DOI:10.1039/c9cc07322a

Reference yield:

(2,6-diisopropylphenyl)-3,4-perylenedicarboxylic imide anion radical → N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide (165550-61-8) + (2,6-diisopropylphenyl)-3,4-perylenedicarboxylic imide dianion

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); In chloroform; acetonitrile; Equilibrium constant; cyclovoltammetry;

DOI:10.1021/ja984188m

upstream raw materials:

2,6-diisopropylbenzenamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

N-(2,6-diisopropylphenyl)-4,5-dibromonaphthalene-1,8-dicarboximide

1-naphthylboronic acid pinacol ester

Downstream raw materials:

N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide

8-bromo-5,12-bis(4-(tert-butyl)phenoxy)-2-(2,6-diisopropylphenyl)-1H-benzo[5,10]anthra[2,1,9-def]isoquinoline-1,3(2H)-dione

N,N'-bis(2,6-diisopropylphenyl)-9,9'-biperylene-3,4:3',4'-bis(dicarboximide)

N,N’-bis-(N-2,6-diisopropylphenyl)quaterrylene-3,4:13,14-bis(dicarboximide)