bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate

Base Information

• Chemical Name: bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate
• CAS No.: 64387-53-7
• Molecular Formula: C₅₁H₄₄ClOP₄Pt₂*F₆P
• Molecular Weight: 1367.38

Synonyms:bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate

Chemical Property of bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate

Chemical Property:

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Technology Process of bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate

There total 3 articles about bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

ammonium hexafluorophosphate + dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) (61250-65-5) → bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate (64387-53-7)

Guidance literature:

With carbon monoxide; In methanol; bubbling CO through suspn. of Pt-complex for 25 min (dissoln.), filtrtaion, addn. of 12% NH4PF6 to filtrate (pptn.); filtration, washing (MeOH), drying (vac.); elem. anal.;

DOI:10.1039/DT9780001540

Reference yield:

[Pt2Cl(THF)(bis(diphenylphosphino)methane)2]PF6 → bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate (64387-53-7)

Guidance literature:

With carbon monoxide; In dichloromethane; rapid react.;

DOI:10.1021/ja00414a050

Reference yield:

{Pt2(CO)Cl(μ-1,2-bis(diphenylphosphino)methane)2}Cl (64387-52-6) + hexafluorophosphate anion → bis-μ-bis(diphenylphosphino)methane-carbonylplatinum(I)-chloroplatinum(I)(Pt-Pt) hexafluorophosphate (64387-53-7)

Guidance literature:

In methanol;

DOI:10.1016/S0020-1693(00)94729-7

upstream raw materials:

{Pt2(CO)Cl(μ-1,2-bis(diphenylphosphino)methane)2}Cl

dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I)

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