dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I)

Base Information

• Chemical Name: dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I)
• CAS No.: 61250-65-5
• Molecular Formula: C₅₀H₄₄Cl₂P₄Pt₂
• Molecular Weight: 1229.86
• Mol file: 61250-65-5.mol

Synonyms:dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I)

Chemical Property of dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I)

There total 10 articles about dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + {PtH2(μ-H)(μ-dppm)2}PF6 (63911-00-2) → bis-μ-[bis(diphenylphosphino)methane]-bis(chloroplatinum)(Pt-Pt) (54766-31-3,37701-43-2,61250-65-5)

Guidance literature:

In methanol; refluxing for 15 min; concn., IR identification;

Reference yield: 67.0%

dichlorobis(diethyl sulfide)platinum (14873-92-8) + tetrakis(triphenylphosphine)platinum (14221-02-4) + bis-diphenylphosphinomethane (2071-20-7) → dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) (61250-65-5)

Guidance literature:

In benzene; under nitrogen, addn. of the phosphine to a soln of Pt(PPh3)4 in benzene, addn. of the dichloro Pt complex, reflux for 1 h, cooling to room temp., pptn.; filtration, washing (benzene), drying in vac. for 3 h, cryst., elem. anal.;

DOI:10.1016/S0020-1693(00)92333-8

Reference yield: 40.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + tetrakis(triphenylphosphine)platinum (14221-02-4) + bis-diphenylphosphinomethane (2071-20-7) → dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) (61250-65-5)

Guidance literature:

In benzene; under N2 or Ar, refluxing Pt(PPh3)4, the phosphine and PtCl2(COD) in benzene;

DOI:10.1016/S0020-1693(00)92333-8

upstream raw materials:

dichlorobis(diethyl sulfide)platinum

tetrakis(triphenylphosphine)platinum

bis-diphenylphosphinomethane

dichloro(1,5-cyclooctadiene)platinum(ll)

Downstream raw materials:

{Pt(bis(diphenylphosphino)methane)(BH₂(CN)2)}2

{Pt₂(dppm)2(CH₃CN)2}(BF₄)2

Pt₂Cl₂(S)(CH₂(P(C₆H₅)2)2)2

C₅₂H₄₇ClNP₄Pt₂⁽¹⁺⁾