C₃₁H₂₀AuF₄NO

Base Information

• Chemical Name: C₃₁H₂₀AuF₄NO
• CAS No.: 1617508-02-7
• Molecular Formula: C₃₁H₂₀AuF₄NO
• Molecular Weight: 695.466
• Mol file: 1617508-02-7.mol

Synonyms:C₃₁H₂₀AuF₄NO

Chemical Property of C₃₁H₂₀AuF₄NO

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₁H₂₀AuF₄NO

There total 5 articles about C₃₁H₂₀AuF₄NO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + ethoxy pentafluorobenzene (776-39-6) + C43H30AuF5N2O2 (1617508-01-6) → C31H20AuF4NO (1617508-02-7)

Guidance literature:

ethoxy pentafluorobenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

(tetrahydrothiophene)gold(I) chloride; at 10 ℃; for 3h; Inert atmosphere;

C₄₃H₃₀AuF₅N₂O₂; for 1h; Inert atmosphere;

DOI:10.1039/c4dt01016g

Reference yield:

N-(2,5-di-tert-butylphenyl)-9-amino-perylene-3,4-dicarboximide → C31H20AuF4NO (1617508-02-7)

Guidance literature:

Multi-step reaction with 4 steps

1.1: hydrogenchloride / toluene / 1 h / Inert atmosphere; Reflux

2.1: triethylamine; bis(trichloromethyl) carbonate / dichloromethane / 5 h / Inert atmosphere

3.1: dichloromethane / 1 h / Inert atmosphere

4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

4.2: 3 h / 10 °C / Inert atmosphere

4.3: 1 h / Inert atmosphere

With hydrogenchloride; n-butyllithium; bis(trichloromethyl) carbonate; triethylamine; In tetrahydrofuran; hexane; dichloromethane; toluene;

DOI:10.1039/c4dt01016g

Reference yield:

9-bromo-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide (165261-51-8) → C31H20AuF4NO (1617508-02-7)

Guidance literature:

Multi-step reaction with 6 steps

1.1: sodium t-butanolate; (±)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl; tris-(dibenzylideneacetone)dipalladium(0) / Inert atmosphere

2.1: hydrogenchloride / water; tetrahydrofuran / Inert atmosphere

3.1: hydrogenchloride / toluene / 1 h / Inert atmosphere; Reflux

4.1: triethylamine; bis(trichloromethyl) carbonate / dichloromethane / 5 h / Inert atmosphere

5.1: dichloromethane / 1 h / Inert atmosphere

6.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

6.2: 3 h / 10 °C / Inert atmosphere

6.3: 1 h / Inert atmosphere

With hydrogenchloride; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; n-butyllithium; bis(trichloromethyl) carbonate; (±)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl; triethylamine; sodium t-butanolate; In tetrahydrofuran; hexane; dichloromethane; water; toluene;

DOI:10.1039/c4dt01016g

upstream raw materials:

C₄₉H₄₀N₂O₂

9-bromo-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

(tetrahydrothiophene)gold(I) chloride

ethoxy pentafluorobenzene

Refernces