(+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol

Base Information

Chemical Name:(+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol
CAS No.:170311-04-3
Molecular Formula:C₁₅H₂₄O₃
Molecular Weight:252.354
Hs Code.:

Synonyms:(+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol

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Chemical Property of (+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol

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Technology Process of (+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol

There total 4 articles about (+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 170311-03-2
(+)-(1'S,3'S)-(Z)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2-penten-4-yn-1-ol

: 170311-04-3
(+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol

Guidance literature:: With sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; Ambient temperature;
DOI:10.1016/0031-9422(95)00374-G

Reference yield:

: 41967-81-1
(Z)-3-Methyl-2-penten-4-ynyl tetrahydropyranyl ether

: 170311-04-3
(+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) EtBr, Mg / 1) THF, 0-5 deg C, 30 min, room temp. (30 min); 2) THF, room temp. overnight

2: 92 percent / HOAc / H₂O; tetrahydrofuran / 48 h / Ambient temperature

3: 77 percent / sodium bis-(2-methoxyethoxy)aluminium hydride / tetrahydrofuran / Ambient temperature

With ethidium Bromide; magnesium; acetic acid; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; water;
DOI:10.1016/0031-9422(95)00374-G

Reference yield:

: (-)-(S)-2,2-dimethyl-6-methylene-3-tetrahydropyranoxy-1-cyclohexanone

: 170311-04-3
(+)-(1'S,3'S)-(2Z,4E)-5-(1',3'-dihydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,4-pentadiene-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) EtBr, Mg / 1) THF, 0-5 deg C, 30 min, room temp. (30 min); 2) THF, room temp. overnight

2: 92 percent / HOAc / H₂O; tetrahydrofuran / 48 h / Ambient temperature

3: 77 percent / sodium bis-(2-methoxyethoxy)aluminium hydride / tetrahydrofuran / Ambient temperature

With ethidium Bromide; magnesium; acetic acid; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; water;
DOI:10.1016/0031-9422(95)00374-G