Rh(bis(triphenylphosphine))(CO₃)(dimethyldithiocarbamato)*CH₂Cl₂

Base Information

• Chemical Name: Rh(bis(triphenylphosphine))(CO₃)(dimethyldithiocarbamato)*CH₂Cl₂
• CAS No.: 129621-15-4
• Molecular Formula: CH₂Cl₂*C₄₀H₃₆NO₃P₂RhS₂
• Molecular Weight: 892.649

Synonyms:Rh(bis(triphenylphosphine))(CO₃)(dimethyldithiocarbamato)*CH₂Cl₂

Chemical Property of Rh(bis(triphenylphosphine))(CO₃)(dimethyldithiocarbamato)*CH₂Cl₂

Chemical Property:

Purity/Quality:

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Technology Process of Rh(bis(triphenylphosphine))(CO₃)(dimethyldithiocarbamato)*CH₂Cl₂

There total 3 articles about Rh(bis(triphenylphosphine))(CO₃)(dimethyldithiocarbamato)*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium (22470-07-1) → Rh(bis(triphenylphosphine))(CO3)(dimethyldithiocarbamato)*CH2Cl2 (129621-15-4)

Guidance literature:

With O₂; CO₂; In dichloromethane; soln. of Rh compd. and PPh3 stirred under atmosphere of O2 for 10 min; then stream of CO2 bubbled through soln. for several min.,; concn. after 4 h, addn. of hexane, pptn., recrystn. from CH2Cl2/hexane, elem. anal.;

Reference yield: 10.0%

bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium (22470-07-1) → Rh(bis(triphenylphosphine))(CO4)(dimethyldithiocarbamato)*0.5CH2Cl2 + Rh(bis(triphenylphosphine))(CO3)(dimethyldithiocarbamato)*CH2Cl2 (129621-15-4)

Guidance literature:

With CO₂; O₂; In benzene; through a soln. of Rh compd., triphenylphosphine in benzene were slowly bubbled CO2 gas and O2 for 30 min at room temp.; yellow ppt. washed with benzene, recrystn. from CH2Cl2/hexane in the presence of PPh3 gave peroxocarbamato compd. and small amt. of carbamato complex, which was mechanically removed; elem. anal. for peroxocarbamato compd.;

Reference yield:

Rh(bis(triphenylphosphine))(CO4)(dimethyldithiocarbamato)*0.5CH2Cl2 → Rh(bis(triphenylphosphine))(CO3)(dimethyldithiocarbamato)*CH2Cl2 (129621-15-4)

Guidance literature:

In dichloromethane-d2; NMR tube; room temp. in the presence of 4 equimolar amts. of PPh3, reaction monitored by (1)H and (31)P NMR spectroscopy;

upstream raw materials:

bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

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