furan-2-carboxylic acid 3-phenylallyl ester

Base Information

• Chemical Name: furan-2-carboxylic acid 3-phenylallyl ester
• CAS No.: 666213-48-5
• Molecular Formula: C₁₄H₁₂O₃
• Molecular Weight: 228.247
• Mol file: 666213-48-5.mol

Synonyms:furan-2-carboxylic acid 3-phenylallyl ester

Chemical Property of furan-2-carboxylic acid 3-phenylallyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of furan-2-carboxylic acid 3-phenylallyl ester

There total 6 articles about furan-2-carboxylic acid 3-phenylallyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

1-phenylallyl furan-2-carboxylate → furan-2-carboxylic acid 3-phenylallyl ester (666213-48-5) + 3-oxo-3-phenylpropyl furan-2-carboxylate + 3-oxo-1-phenylpropyl furan-2-carboxylate

Guidance literature:

With bis(benzonitrile)palladium(II) dichloride; p-benzoquinone; In acetone; tert-butyl alcohol; at 20 ℃; regioselective reaction; Inert atmosphere;

DOI:10.1002/anie.201301809

Reference yield: 42.0%

furfural (98-01-1) + 3-bromo-1-phenyl-1-propenyl bromide (4392-24-9) → furan-2-carboxylic acid 3-phenylallyl ester (666213-48-5)

Guidance literature:

With oxygen; 1,3-dibenzyl-1H-benzo[d]imidazol-3-ium chloride; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; tert-butyl alcohol; at 25 ℃; for 48h;

DOI:10.1021/jo200275c

Reference yield: 37.0%

3-Phenylpropenol (104-54-1) + 2-thiolomethyl-furan (98-02-2,175236-33-6) → furan-2-carboxylic acid 3-phenylallyl ester (666213-48-5)

Guidance literature:

With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine; oxygen; copper dichloride; In toluene; at 20 ℃; for 18h; under 760.051 Torr;

DOI:10.1002/ejoc.201403311

upstream raw materials:

furfural

3-bromo-1-phenyl-1-propenyl bromide

3-Phenylpropenol

benzaldehyde