methyl 2,3,4-tri-O-benzyl-5,7-di-O-(4-pentenoyl)-β-D-glycero-D-guloseptanoside

Base Information

• Chemical Name: methyl 2,3,4-tri-O-benzyl-5,7-di-O-(4-pentenoyl)-β-D-glycero-D-guloseptanoside
• CAS No.: 1021441-31-5
• Molecular Formula: C₃₉H₄₆O₉
• Molecular Weight: 658.789
• Mol file: 1021441-31-5.mol

Synonyms:methyl 2,3,4-tri-O-benzyl-5,7-di-O-(4-pentenoyl)-β-D-glycero-D-guloseptanoside

Chemical Property of methyl 2,3,4-tri-O-benzyl-5,7-di-O-(4-pentenoyl)-β-D-glycero-D-guloseptanoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2,3,4-tri-O-benzyl-5,7-di-O-(4-pentenoyl)-β-D-glycero-D-guloseptanoside

There total 1 articles about methyl 2,3,4-tri-O-benzyl-5,7-di-O-(4-pentenoyl)-β-D-glycero-D-guloseptanoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methyl 2,3,4-tri-O-benzyl-β-D-glycero-D-guloseptanoside (1021441-28-0) + pent-4-enoyl chloride (39716-58-0) → methyl 2,3,4-tri-O-benzyl-5,7-di-O-(4-pentenoyl)-β-D-glycero-D-guloseptanoside (1021441-31-5)

Guidance literature:

With pyridine; dmap; at 80 ℃; for 16h;

DOI:10.1021/jo800027y

Reference yield: 63.0%

methyl 2,3,4-tri-O-benzyl-5,7-di-O-(4-pentenoyl)-β-D-glycero-D-guloseptanoside (1021441-31-5) → methyl 2,3,4-tri-O-benzyl-5,7-O-(E-oct-4-enedioyl)-β-D-glycero-D-guloseptanoside (1021441-23-5)

Guidance literature:

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In toluene; Heating;

DOI:10.1021/jo800027y

upstream raw materials:

methyl 2,3,4-tri-O-benzyl-β-D-glycero-D-guloseptanoside

pent-4-enoyl chloride

Downstream raw materials:

methyl 2,3,4-tri-O-benzyl-5,7-O-(E-oct-4-enedioyl)-β-D-glycero-D-guloseptanoside