[(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane

Base Information

Chemical Name:[(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane
CAS No.:211758-07-5
Molecular Formula:C₂₇H₃₈O₃Si
Molecular Weight:438.682
Hs Code.:

Synonyms:[(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane

Suppliers and Price of [(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of [(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane

There total 8 articles about [(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 106-95-6
allyl bromide

: 211758-00-8
(S)-5-(tert-Butyl-diphenyl-silanyloxy)-1-((S)-2-methyl-oxiranyl)-pentan-2-ol

: 211758-07-5
[(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: With tetra-(n-butyl)ammonium iodide; potassium hydride; In 1,2-dimethoxyethane; at 0 ℃;
DOI:10.1016/S0040-4039(98)00971-X

Reference yield:

: 211758-06-4
(S)-6-Methyl-hept-6-ene-1,4-diol

: 211758-07-5
[(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / imidazole / CH₂Cl₂ / 0 °C

2: 21 percent / I₂, nBuLi / tetrahydrofuran

3: 92 percent / KOH / 1,2-dimethoxy-ethane

4: 84 percent / KH, Bu₄NI / 1,2-dimethoxy-ethane / 0 °C

With 1H-imidazole; potassium hydroxide; n-butyllithium; iodine; tetra-(n-butyl)ammonium iodide; potassium hydride; In tetrahydrofuran; 1,2-dimethoxyethane; dichloromethane;
DOI:10.1016/S0040-4039(98)00971-X

Reference yield:

: 211757-95-8
(R)-5-(2-Methyl-allyl)-5H-furan-2-one

: 211758-07-5
[(S)-4-Allyloxy-5-((S)-2-methyl-oxiranyl)-pentyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 90 percent / NaBH₄, CuCl*2H₂O / methanol / 0 °C

2: 92 percent / LiAlH₄ / tetrahydrofuran / 0 °C

3: 98 percent / imidazole / CH₂Cl₂ / 0 °C

4: 21 percent / I₂, nBuLi / tetrahydrofuran

5: 92 percent / KOH / 1,2-dimethoxy-ethane

6: 84 percent / KH, Bu₄NI / 1,2-dimethoxy-ethane / 0 °C

With 1H-imidazole; potassium hydroxide; sodium tetrahydroborate; lithium aluminium tetrahydride; n-butyllithium; iodine; tetra-(n-butyl)ammonium iodide; potassium hydride; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; dichloromethane;
DOI:10.1016/S0040-4039(98)00971-X