9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol

Base Information

• Chemical Name: 9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol
• CAS No.: 858856-49-2
• Molecular Formula: C₂₈H₂₄O₄
• Molecular Weight: 424.496
• Mol file: 858856-49-2.mol

Synonyms:9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol

Chemical Property of 9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol

There total 5 articles about 9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.9%

1-bromo-4-methoxy-benzene (104-92-7) + 9,10-phenanthrenequinone (84-11-7) → 9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol (858856-49-2)

Guidance literature:

1-bromo-4-methoxy-benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

9,10-phenanthrenequinone; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

With water; In tetrahydrofuran; hexane; at 20 ℃;

DOI:10.1021/ol702873z

Reference yield:

4-methoxyphenyl magnesium bromide (13139-86-1) + 9,10-phenanthrenequinone (84-11-7) → 9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol (858856-49-2)

Guidance literature:

With diethyl ether; benzene; optically inactive stereoisomer(ic) of mp: 157 degree;

DOI:10.1021/ja01344a036

Reference yield:

2,2'-bis(4-methoxybenzoyl)biphenyl (20837-34-7) → 9,10-di(4-methoxyphenyl)-9,10-dihydro-phenanthrene-9,10-diol (858856-49-2)

Guidance literature:

With diethyl ether; magnesium; magnesium iodide; optically inactive stereoisomer(ic) of mp: 190 degree; weiteres Reagens: Benzol;

DOI:10.1021/ja01344a036

upstream raw materials:

2,2'-bis(4-methoxybenzoyl)biphenyl

4-methoxyphenyl magnesium bromide

9,10-phenanthrenequinone

1-bromo-4-methoxy-benzene

Downstream raw materials:

10,10-di-p-anisyl-9,10-dihydro-9-phenanthrenone

9,10-bis (4-methoxyphenyl)phenanthrene