2-{(3S,1E)-3-[(1S,2S)-2-allyl-2-methyl-3-oxocyclopentyl]-5-(2-bromo-5-methoxyphenyl)pent-1-enyl}-(3aR,7aR)-1,3-dimethyl-octahydrobenzo[1,3,2]diazaphosphole 2-oxide

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Chemical Name:2-{(3S,1E)-3-[(1S,2S)-2-allyl-2-methyl-3-oxocyclopentyl]-5-(2-bromo-5-methoxyphenyl)pent-1-enyl}-(3aR,7aR)-1,3-dimethyl-octahydrobenzo[1,3,2]diazaphosphole 2-oxide
CAS No.:1207541-77-2
Molecular Formula:C₂₉H₄₂BrN₂O₃P
Molecular Weight:577.542
Hs Code.:

2-{(3S,1E)-3-[(1S,2S)-2-allyl-2-methyl-3-oxocyclopentyl]-5-(2-bromo-5-methoxyphenyl)pent-1-enyl}-(3aR,7aR)-1,3-dimethyl-octahydrobenzo[1,3,2]diazaphosphole 2-oxide

Synonyms:2-{(3S,1E)-3-[(1S,2S)-2-allyl-2-methyl-3-oxocyclopentyl]-5-(2-bromo-5-methoxyphenyl)pent-1-enyl}-(3aR,7aR)-1,3-dimethyl-octahydrobenzo[1,3,2]diazaphosphole 2-oxide

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Chemical Property of 2-{(3S,1E)-3-[(1S,2S)-2-allyl-2-methyl-3-oxocyclopentyl]-5-(2-bromo-5-methoxyphenyl)pent-1-enyl}-(3aR,7aR)-1,3-dimethyl-octahydrobenzo[1,3,2]diazaphosphole 2-oxide

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Technology Process of 2-{(3S,1E)-3-[(1S,2S)-2-allyl-2-methyl-3-oxocyclopentyl]-5-(2-bromo-5-methoxyphenyl)pent-1-enyl}-(3aR,7aR)-1,3-dimethyl-octahydrobenzo[1,3,2]diazaphosphole 2-oxide

There total 1 articles about 2-{(3S,1E)-3-[(1S,2S)-2-allyl-2-methyl-3-oxocyclopentyl]-5-(2-bromo-5-methoxyphenyl)pent-1-enyl}-(3aR,7aR)-1,3-dimethyl-octahydrobenzo[1,3,2]diazaphosphole 2-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 1120-73-6
2-methyl-2-cyclopenten-1-one

: 1207541-76-1
2-[(2Z)-5-(2-bromo-5-methoxy-phenyl)-pent-2-enyl]-1,3-dimethyloctahydrobenzo[1,3,2]diazaphosphole 2-oxide

: 106-95-6
allyl bromide

: C₂₆H₃₈BrN₂O₃P

: 1207541-77-2
2-{(3S,1E)-3-[(1S,2S)-2-allyl-2-methyl-3-oxocyclopentyl]-5-(2-bromo-5-methoxyphenyl)pent-1-enyl}-(3aR,7aR)-1,3-dimethyl-octahydrobenzo[1,3,2]diazaphosphole 2-oxide

: C₃₂H₄₆BrN₂O₃P

Guidance literature:: 2-[(2Z)-5-(2-bromo-5-methoxy-phenyl)-pent-2-enyl]-1,3-dimethyloctahydrobenzo[1,3,2]diazaphosphole 2-oxide; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; Inert atmosphere;

2-methyl-2-cyclopenten-1-one; In tetrahydrofuran; hexane; at 0 ℃; for 1h; Inert atmosphere;

allyl bromide; In tetrahydrofuran; hexane; at 0 - 20 ℃; optical yield given as %de; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol902638w