[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]

Base Information

• Chemical Name: [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]
• CAS No.: 922725-08-4
• Molecular Formula: C₃₃H₄₂NiPS₃SeSi₃*C₃₆H₃₀NP₂
• Molecular Weight: 1326.36

Synonyms:[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]

Chemical Property of [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]

Chemical Property:

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Safty Information:

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Technology Process of [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]

There total 1 articles about [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

[bis(triphenylphosphoranylidene)ammonium][Ni(CO)(SePh)3] (196961-63-4) + 2,2',2-trimercapto-3,3',3-tris(trimethylsilyl)triphenylphosphine (119327-24-1) → [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C6H3-3-SiMe3-2-S)2(o-C6H3-3-SiMe3-2-SH))] (922725-08-4)

Guidance literature:

In tetrahydrofuran; (under N2, Schlenk); Ni-complex and ligand mixed in THF, stirred at ambient temp. for 1 h; hexane added, Et2O diffused at room temp. for 1 wk; elem. anal.;

DOI:10.1021/ic061399g

Reference yield: 70.0%

[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C6H3-3-SiMe3-2-S)2(o-C6H3-3-SiMe3-2-SH))] (922725-08-4) → [Ni(P(o-C6H3-3-SiMe3-2-S)2(o-C6H3-3-SiMe3-2-SH))]2 (956107-45-2)

Guidance literature:

With [(C₂H₅)3O][BF₄]; In tetrahydrofuran; byproducts: N(P(C6H5)3)2BF4; (N2); (C2H5)3OBF4 added slowly to a soln. of Ni complex at 5°C; hexane added, filtered, evapd. (vac.);

DOI:10.1021/ic700719h

Reference yield: 60.0%

[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C6H3-3-SiMe3-2-S)2(o-C6H3-3-SiMe3-2-SH))] (922725-08-4) + water-d2 (7789-20-0) → (bis(triphenylphosphoranylidene))[Ni(SePh)(P(C6H3-3-SiMe3-2-S)2(C6H3-3-SiMe3-2-SD)]

Guidance literature:

In tetrahydrofuran; (under N2, Schlenk); D2O added to THF soln. of Ni-complex at 5°C,stirred for 24 h; hexane added, sealed, kept at room temp. for 1 wk;

DOI:10.1021/ic061399g

upstream raw materials:

[bis(triphenylphosphoranylidene)ammonium][Ni(CO)(SePh)3]

2,2',2-trimercapto-3,3',3-tris(trimethylsilyl)triphenylphosphine

Downstream raw materials:

[Ni(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]2

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