<4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane

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Chemical Name:<4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane
CAS No.:125830-13-9
Molecular Formula:C₂₃H₃₈O₃Si
Molecular Weight:390.638
Hs Code.:

Synonyms:<4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane

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Chemical Property of <4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane

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Technology Process of <4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane

There total 4 articles about <4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 60656-87-3
benzyloxyacetoaldehyde

: 125830-13-9
<4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane

Guidance literature:: Multi-step reaction with 5 steps

2: 1.) Me₃Al / 1.) THF, toluene, from 0 deg C to RT, 25 min, 2.) CH₂Cl₂, 0 deg C, 3 h

3: 1.) lithium / 1.) Et₂O, from 0 deg C to RT, 14.5 h, 2.) THF, -78 deg C, 40 min

4: 99 percent / methoxydiethylborane, NaBH₄ / tetrahydrofuran; methanol / 4 h / -70 °C

5: 97 percent / 2,6-lutidine / CH₂Cl₂ / 9 h / 65 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; diethyl methoxy borane; trimethylaluminum; lithium; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ja00175a038

Reference yield:

: 129986-20-5
<2R,3R>-3-hydroxy-N-methoxy-N,2-dimethyl-4-(phenylmethoxy)butanamide

: 125830-13-9
<4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) lithium / 1.) Et₂O, from 0 deg C to RT, 14.5 h, 2.) THF, -78 deg C, 40 min

2: 99 percent / methoxydiethylborane, NaBH₄ / tetrahydrofuran; methanol / 4 h / -70 °C

3: 97 percent / 2,6-lutidine / CH₂Cl₂ / 9 h / 65 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; diethyl methoxy borane; lithium; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ja00175a038

Reference yield:

: 129986-19-2
<3(2R,3R),4R,5S>-3-<3-hydroxy-2-methyl-1-oxo-4-(phenylmethoxy)butyl>-4-methyl-5-phenyl-2-oxazolidinone

: 125830-13-9
<4S,5S,6R>-2,2-bis(1,1-dimethylethyl)-5-methyl-4-(1-methylethenyl)-6-<(phenylmethoxy)methyl>1,3-dioxa-2-silacyclohexane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Me₃Al / 1.) THF, toluene, from 0 deg C to RT, 25 min, 2.) CH₂Cl₂, 0 deg C, 3 h

2: 1.) lithium / 1.) Et₂O, from 0 deg C to RT, 14.5 h, 2.) THF, -78 deg C, 40 min

3: 99 percent / methoxydiethylborane, NaBH₄ / tetrahydrofuran; methanol / 4 h / -70 °C

4: 97 percent / 2,6-lutidine / CH₂Cl₂ / 9 h / 65 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; diethyl methoxy borane; trimethylaluminum; lithium; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ja00175a038