<2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

Base Information

Chemical Name:<2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol
CAS No.:149157-48-2
Molecular Formula:C₃₂H₅₀O₄Si
Molecular Weight:526.832
Hs Code.:

Synonyms:<2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

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Chemical Property of <2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

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Technology Process of <2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

There total 6 articles about <2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 149157-47-1
<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

: 149157-48-2
<2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at 0 ℃;
DOI:10.1016/S0040-4039(00)77580-0

Reference yield:

: 141423-25-8
<<3-(2R,4S,5S,6R,8E),4R>-3-(5-Hydroxy-2,4,6-trimethyl-1,3-dioxo-9-phenyl-8-nonenyl)-4-(phenylmethyl)>-2-oxazolidinone

: 149157-48-2
<2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

Guidance literature:: Multi-step reaction with 5 steps

1: 81 percent / NaBH(OAc)3, AcOH / 1 h / 23 °C

2: 94 percent / LiBH₄ / methanol; tetrahydrofuran / 1 h / 0 °C

3: 91 percent / camphorsulfonic acid / dimethylformamide / 12 h / 23 °C

4: 100 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

5: 100 percent / diisobutylaluminum hydride / CH₂Cl₂ / 6 h / 0 °C

With 2,6-dimethylpyridine; lithium borohydride; camphor-10-sulfonic acid; sodium tris(acetoxy)borohydride; diisobutylaluminium hydride; acetic acid; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00077a049

Reference yield:

: 149157-45-9
<2S,3S,4S,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-non-8-ene-1,3,5-triol

: 149157-48-2
<2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / camphorsulfonic acid / dimethylformamide / 12 h / 23 °C

2: 100 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

3: 100 percent / diisobutylaluminum hydride / CH₂Cl₂ / 6 h / 0 °C

With 2,6-dimethylpyridine; camphor-10-sulfonic acid; diisobutylaluminium hydride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00077a049