6-(tert-butyldiphenylsilyloxy)-5-hydroxy-5-methyl-2-methylenehexyl acetate

Base Information

• Chemical Name: 6-(tert-butyldiphenylsilyloxy)-5-hydroxy-5-methyl-2-methylenehexyl acetate
• CAS No.: 1012075-32-9
• Molecular Formula: C₂₆H₃₆O₄Si
• Molecular Weight: 440.655
• Mol file: 1012075-32-9.mol

Synonyms:6-(tert-butyldiphenylsilyloxy)-5-hydroxy-5-methyl-2-methylenehexyl acetate

Chemical Property of 6-(tert-butyldiphenylsilyloxy)-5-hydroxy-5-methyl-2-methylenehexyl acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-(tert-butyldiphenylsilyloxy)-5-hydroxy-5-methyl-2-methylenehexyl acetate

There total 1 articles about 6-(tert-butyldiphenylsilyloxy)-5-hydroxy-5-methyl-2-methylenehexyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

6-(tert-butyldiphenylsilyloxy)-5-methyl-2-methylenehexane-1,5-diol (1012075-09-0) + acetic anhydride (108-24-7) → 6-(tert-butyldiphenylsilyloxy)-5-hydroxy-5-methyl-2-methylenehexyl acetate (1012075-32-9)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/jo702620e

Reference yield: 90.0%

6-(tert-butyldiphenylsilyloxy)-5-hydroxy-5-methyl-2-methylenehexyl acetate (1012075-32-9) → (tert-butyl)(2-methyl-5-methylenetetrahydropyran-2-ylmethoxy)diphenylsilane (1012075-20-5)

Guidance literature:

With titanium(IV) isopropylate; triphenylphosphine; palladium diacetate; In toluene; for 1.5h; Heating;

DOI:10.1021/jo702620e

upstream raw materials:

6-(tert-butyldiphenylsilyloxy)-5-methyl-2-methylenehexane-1,5-diol

acetic anhydride

Downstream raw materials:

(tert-butyl)(2-methyl-5-methylenetetrahydropyran-2-ylmethoxy)diphenylsilane