di-(2,2,2-trifluoroethyl)chlorophosphate

Base Information

• Chemical Name: di-(2,2,2-trifluoroethyl)chlorophosphate
• CAS No.: 40547-38-4
• Molecular Formula: C₄H₅F₆O₄P
• Molecular Weight: 262.045
• Mol file: 40547-38-4.mol

Synonyms:di-(2,2,2-trifluoroethyl)chlorophosphate

Chemical Property of di-(2,2,2-trifluoroethyl)chlorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of di-(2,2,2-trifluoroethyl)chlorophosphate

There total 3 articles about di-(2,2,2-trifluoroethyl)chlorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.7%

tris(2,2,2-trifluoroethyl) phosphate (358-63-4) → di-(2,2,2-trifluoroethyl)chlorophosphate (40547-38-4)

Guidance literature:

With potassium hydroxide; for 0.5h; Heating;

DOI:10.1007/BF00954148

Reference yield:

bis(2,2,2-trifluoroethyl) chlorophosphate (381-44-2) → tris(2,2,2-trifluoroethyl) phosphate (358-63-4) + di-(2,2,2-trifluoroethyl)chlorophosphate (40547-38-4) + C8H8F12O7P2

Guidance literature:

With dmap; 3-sulfanylpropanol; triethylamine; In diethyl ether; at 0 - 20 ℃; for 12h; Title compound not separated from byproducts;

DOI:10.1016/S0022-1139(02)00239-7

Reference yield:

C11H16F9N3O3P(1+)*F6P(1-) → tris(2,2,2-trifluoroethyl) phosphate (358-63-4) + di-(2,2,2-trifluoroethyl)chlorophosphate (40547-38-4) + 2-amino-1,3-dimethylimidazolinium hexafluorophosphate

Guidance literature:

With water;

DOI:10.1016/j.ica.2017.05.075

upstream raw materials:

tris(2,2,2-trifluoroethyl) phosphate

bis(2,2,2-trifluoroethyl) chlorophosphate