C₉H₆BrFO

Base Information

• Chemical Name: C₉H₆BrFO
• CAS No.: 1428869-63-9
• Molecular Formula: C₉H₆BrFO
• Molecular Weight: 229.048
• Mol file: 1428869-63-9.mol

Synonyms:C₉H₆BrFO

Chemical Property of C₉H₆BrFO

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₉H₆BrFO

There total 3 articles about C₉H₆BrFO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

(E)-3-(2-bromo-5-fluorophenyl)prop-2-en-1-ol (1428869-66-2) → C9H6BrFO (1428869-63-9)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tetlet.2013.02.039

Reference yield:

ethyl (2E)-3-(2-bromo-5-fluorophenyl)prop-2-enoate (1019852-40-4) → C9H6BrFO (1428869-63-9)

Guidance literature:

Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / hexane; dichloromethane / 3 h / 0 °C / Inert atmosphere

2: manganese(IV) oxide / dichloromethane / 1 h / 20 °C / Inert atmosphere

With manganese(IV) oxide; diisobutylaluminium hydride; In hexane; dichloromethane;

DOI:10.1016/j.tetlet.2013.02.039

Reference yield:

→ C9H6BrFO (1428869-63-9)

Guidance literature:

In toluene; at 85 ℃; for 18h;

upstream raw materials:

(E)-3-(2-bromo-5-fluorophenyl)prop-2-en-1-ol

ethyl (2E)-3-(2-bromo-5-fluorophenyl)prop-2-enoate

Downstream raw materials:

(E)-2-(4,4-bis((trifluoromethyl)sulfonyl)but-1-en-1-yl)-1-bromo-4-fluorobenzene

(E)-2-(4,4-bis((trifluoromethyl)sulfonyl)buta-1,3-dienyl)-1-bromo-4-fluorobenzene