methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate

Base Information

• Chemical Name: methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate
• CAS No.: 202803-47-2
• Molecular Formula: C₂₆H₄₁N₉O₁₁
• Molecular Weight: 655.665
• Mol file: 202803-47-2.mol

Synonyms:methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate

Chemical Property of methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate

There total 9 articles about methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

methyl galloate (99-24-1) → methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate (202803-47-2)

Guidance literature:

With tetrabutylammomium bromide; potassium carbonate; In [⁽²⁾H₆]acetone; water; ethyl acetate;

Reference yield: 72.0%

methyl galloate (99-24-1) + 1-azido-2-[2-(2-chloroethoxy) ethoxy] ethane (1301708-62-2) → methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate (202803-47-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 36h; Inert atmosphere;

DOI:10.1016/j.bioorg.2021.104667

Reference yield: 65.0%

methyl galloate (99-24-1) + 8-azido-3,6-dioxaoctyl tosylate (178685-33-1) → methyl 3,4,5-tris(2-(2-(2-azidoethoxy) ethoxy) ethoxy) benzoate (202803-47-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 24h;

DOI:10.1139/v97-177

upstream raw materials:

methyl galloate

8-azido-3,6-dioxaoctyl tosylate

3,4,5-trihydroxybenzoic acid

3,4,5-trihydroxybenzoyl chloride

Downstream raw materials:

3,4,5-tris{2-[2-(2-azidoethoxy)ethoxy]ethoxy}benzoic acid

3,4,5-Tris-(2-{2-[2-(2-chloro-acetylamino)-ethoxy]-ethoxy}-ethoxy)-benzoic acid methyl ester

3,4,5-Tris-{2-[2-(2-amino-ethoxy)-ethoxy]-ethoxy}-benzoic acid methyl ester