hafnocene di((Ph₂)phosphide)

Base Information

Chemical Name:hafnocene di((Ph₂)phosphide)
CAS No.:86013-28-7
Molecular Formula:C₃₄H₃₀HfP₂
Molecular Weight:679.05
Hs Code.:

Synonyms:hafnocene di((Ph₂)phosphide)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of hafnocene di((Ph₂)phosphide)

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of hafnocene di((Ph₂)phosphide)

There total 1 articles about hafnocene di((Ph₂)phosphide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.1%

: 12116-66-4
bis(cyclopentadienyl)hafnium dichloride

: 65567-06-8,4541-02-0
lithium diphenylphosphide

: 86013-28-7
hafnocene di((Ph₂)phosphide)

Guidance literature:: In hexane; benzene; byproducts: LiCl; to suspn. of LiPPh2 in hexane added Hf complex in C6H6, stired for 2 h at room temp., left to stand for 1 h; filtered, residue extd. with C6H6, filtrates combined, concd., pptd. with n-hexane; elem. anal.;

Reference yield: 94.1%

: 86013-28-7
hafnocene di((Ph₂)phosphide)

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 12116-66-4
bis(cyclopentadienyl)hafnium dichloride

Guidance literature:: In benzene; byproducts: P(C6H5)2P(C6H5)2; PPh2Cl injected into soln. of Hf complex in C6H6, stirred for 3 min at room temp.; solvent removed, solid extd. with n-hexane to leave Hf product;

Reference yield: 90.0%

: 86013-28-7
hafnocene di((Ph₂)phosphide)

: η5-indenylbis(ethylene)rhodium(I)

: 100113-61-9
(C₅H₅)2Hf(P(C₆H₅)2)2Rh(C₉H₇)

Guidance literature:: In tetrahydrofuran; byproducts: ethylene; a soln. of Rh complex was added dropwise to a soln. of Hf complex underN2 over 10 min; the resulting dark-red soln. was stirred for 3 d; evapn. to dryness, residue stirred with hexane, filtn., dried in vacuo,recrystallization from THF-heptane; elem. anal.;
DOI:10.1021/om00136a002