2,3-epoxygeranial

Base Information

• Chemical Name: 2,3-epoxygeranial
• CAS No.: 16996-12-6
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.236
• Mol file: 16996-12-6.mol

Synonyms:2,3-epoxygeranial

Chemical Property of 2,3-epoxygeranial

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 2,3-epoxygeranial

There total 5 articles about 2,3-epoxygeranial which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Nerol (106-25-2) → [3-methyl-3-(4-methylpent-3-enyl)oxiran-2-yl]methanol (50727-94-1) + 2,3-epoxygeranial (16996-12-6)

Guidance literature:

Nerol; With C₆₀H₅₀N₂O₂; niobium(V) isopropoxide; In chloroform; sodium chloride; at 40 ℃; for 0.5h;

With dihydrogen peroxide; In chloroform; water; sodium chloride; at 40 ℃; enantioselective reaction;

DOI:10.1021/ja100795k

Reference yield:

Geraniol (106-24-1) → [3-methyl-3-(4-methylpent-3-enyl)oxiran-2-yl]methanol (50727-94-1) + 2,3-epoxygeranial (16996-12-6)

Guidance literature:

Geraniol; With C₆₀H₅₀N₂O₂; niobium(V) isopropoxide; In chloroform; sodium chloride; at 40 ℃; for 0.5h;

With dihydrogen peroxide; In chloroform; water; sodium chloride; at 40 ℃; enantioselective reaction;

DOI:10.1021/ja100795k

Reference yield:

(E/Z)-3,7-dimethyl-2,6-octadienal (5392-40-5,96680-15-8) → 6-Methyl-hept-5-en-2-on (110-93-0,129085-68-3) + 3-methyl-3-(4-methylpent-3-enyl)oxirane-2-carbaldehyde (10070-71-0,16996-12-6,61063-17-0,61063-18-1,105929-77-9,105929-78-0,114762-39-9,119786-65-1) + 3-methyl-3-(4-methylpent-3-enyl)oxirane-2-carbaldehyde

Guidance literature:

With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; dihydrogen peroxide;

DOI:10.1023/B:RUJO.0000003190.03400.91

upstream raw materials:

Nerol

Geraniol

(E/Z)-3,7-dimethyl-2,6-octadienal

Downstream raw materials:

(2S,3S)-2,3-epoxygeraniol

(2R,3R)-3-methyl-3-(4-methyl-3-pentenyl)oxiranemethanol

2-methyl-2-(4-methyl-pent-3-enyl)-oxirane

6-Methyl-hept-5-en-2-on