2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol

Base Information

Chemical Name:2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol
CAS No.:1218787-82-6
Molecular Formula:C₃₆H₃₆O₆S₂
Molecular Weight:628.81
Hs Code.:

Synonyms:2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol

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Chemical Property of 2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol

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Technology Process of 2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol

There total 5 articles about 2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 940000-68-0
6,8,9-tris-benzyloxy-3-phenyl-2,4-dioxa-bicyclo[3.3.1]nonan-7-ol

: 75-15-0,12122-00-8
carbon disulfide

: 74-88-4
methyl iodide

: 1218787-82-6
2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol

Guidance literature:: 6,8,9-tris-benzyloxy-3-phenyl-2,4-dioxa-bicyclo[3.3.1]nonan-7-ol; With sodium hydride; In tetrahydrofuran; mineral oil;

carbon disulfide; In tetrahydrofuran; mineral oil; for 1h; Reflux;

methyl iodide; In tetrahydrofuran; mineral oil; at 20 ℃; for 16h;
DOI:10.1016/j.tet.2011.07.044

Reference yield:

: C₃₅H₃₃O₆S₂^(1-)*Na⁽¹⁺⁾

: 74-88-4
methyl iodide

: 1218787-82-6
2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol

Guidance literature:: In tetrahydrofuran; mineral oil; at 20 ℃; for 16h;
DOI:10.1002/ejoc.200901156

Reference yield:

: 2,4,6-tri-O-benzyl-myo-inositol 1,3,5-orthobenzoate

: 1218787-82-6
2,4,6-tri-O-benzyl-1,3-O-benzylidene-5-O-[(methylthio)thiocarbonyl]myo-inositol

Guidance literature:: Multi-step reaction with 2 steps

1.1: diisobutylaluminium hydride / dichloromethane / 0 °C

2.1: sodium hydride / tetrahydrofuran; mineral oil

2.2: 1 h / Reflux

2.3: 16 h / 20 °C

With sodium hydride; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane; mineral oil;
DOI:10.1016/j.tet.2011.07.044