O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate

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Chemical Name:O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate
CAS No.:1374219-26-7
Molecular Formula:C₂₄H₃₆O₃S₂
Molecular Weight:436.68
Hs Code.:

Synonyms:O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate

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Chemical Property of O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate

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Technology Process of O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate

There total 11 articles about O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1374219-25-6
O-(7S,8S)-7-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-1,4-dioxaspiro[4.5]decan-8-yl S-methyl carbonodithioate

: 1374219-26-7
O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; water; at 20 ℃; for 36h;
DOI:10.1002/adsc.201100898

Reference yield:

: 4683-24-3
1,4-dioxa-spiro[4.5]dec-6-en-8-one

: 1374219-26-7
O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate

Guidance literature:: Multi-step reaction with 6 steps

1.1: dmap; iodine; potassium carbonate / tetrahydrofuran; water / 2 h / 20 °C

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; lithium chloride / 1,2-dimethoxyethane; water / 12 h / 80 °C / Inert atmosphere

3.1: 5%-palladium/activated carbon; hydrogen / ethanol / 3 h / 30 °C / 760.05 Torr

4.1: C₅₅H₅₀Cl₂N₂P₂Ru; potassium tert-butylate; hydrogen / isopropyl alcohol / 12 h / 20 °C / 38002.6 Torr / Inert atmosphere

5.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 - 20 °C / Inert atmosphere

5.2: 0.75 h / 20 °C

5.3: 0.75 h / 20 °C

6.1: hydrogenchloride / tetrahydrofuran; water / 36 h / 20 °C

With hydrogenchloride; dmap; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 5%-palladium/activated carbon; C₅₅H₅₀Cl₂N₂P₂Ru; potassium tert-butylate; hydrogen; iodine; sodium hydride; sodium carbonate; potassium carbonate; lithium chloride; In tetrahydrofuran; 1,2-dimethoxyethane; ethanol; water; isopropyl alcohol; 2.1: Suzuki coupling;
DOI:10.1002/adsc.201100898

Reference yield:

: 866398-21-2
1-(1,1-dimethylheptyl)-3-methoxybenzene

: 1374219-26-7
O-(1S,2S)-2-[2-methoxy-4-(2-methyloctan-2-yl)phenyl]-4-oxocyclohexyl S-methyl carbonodithioate

Guidance literature:: Multi-step reaction with 7 steps

1.1: bromine / acetic acid / 4 h / 20 °C

2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

2.2: 1.5 h / -78 - -30 °C / Inert atmosphere

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; lithium chloride / 1,2-dimethoxyethane; water / 12 h / 80 °C / Inert atmosphere

4.1: 5%-palladium/activated carbon; hydrogen / ethanol / 3 h / 30 °C / 760.05 Torr

5.1: C₅₅H₅₀Cl₂N₂P₂Ru; potassium tert-butylate; hydrogen / isopropyl alcohol / 12 h / 20 °C / 38002.6 Torr / Inert atmosphere

6.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 - 20 °C / Inert atmosphere

6.2: 0.75 h / 20 °C

6.3: 0.75 h / 20 °C

7.1: hydrogenchloride / tetrahydrofuran; water / 36 h / 20 °C

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; 5%-palladium/activated carbon; C₅₅H₅₀Cl₂N₂P₂Ru; potassium tert-butylate; hydrogen; bromine; sodium hydride; sodium carbonate; lithium chloride; In tetrahydrofuran; 1,2-dimethoxyethane; ethanol; water; acetic acid; isopropyl alcohol; 3.1: Suzuki coupling;
DOI:10.1002/adsc.201100898