tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron

Base Information

Chemical Name:tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron
CAS No.:144269-99-8
Molecular Formula:C₂₀H₂₀FeO₄Si
Molecular Weight:408.309
Hs Code.:

Synonyms:tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron

Suppliers and Price of tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron

There total 1 articles about tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 138308-95-9
1-trimethylsilyl-7-phenyl-1,6-heptadiyne

: 144269-99-8
tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron

Guidance literature:: In toluene; High Pressure; addn. of Fe(CO)5 to diyne soln., pressurising with CO (100 psi), heating to 125-130°C for 24 h; cooling, dilution in CH2Cl2, filtration (Celite), evapn. (rotary evaporator), drying (vac.), flash chromy. (20% EtOAc-hexane); elem. anal.;

Reference yield: 98.0%

: 144269-99-8
tricarbonyl(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron

: 144302-72-7
dicarbonyl(triphenylphosphine)(2-(trimethylsilyl)-4-phenylbicyclo{3.3.0}octa-1,4-dien-3-one)iron

Guidance literature:: With P(C₆H₅)3; (CH₃)3NO; In acetone; addn. of PPh3 and Me3NO to Fe-complex soln., refluxing 90 min. (N2); aq. workup, flash chromy. (20% EtOAc-hexane);