5,8-Methanoquinoxaline,2,3,5,8-tetrahydro-9-(1-methylethylidene)-(9CI)

Base Information

Chemical Name:5,8-Methanoquinoxaline,2,3,5,8-tetrahydro-9-(1-methylethylidene)-(9CI)
CAS No.:362050-14-4
Molecular Formula:C₁₂H₁₄N₂
Molecular Weight:186.257
Hs Code.:2933990090
Mol file:362050-14-4.mol

Synonyms:5,8-Methanoquinoxaline,2,3,5,8-tetrahydro-9-(1-methylethylidene)-(9CI);2,3,5,8-TETRAHYDRO-9-(1-METHYLETHYLIDENE)-5,8-METHANOQUINOXALINE

Suppliers and Price of 5,8-Methanoquinoxaline,2,3,5,8-tetrahydro-9-(1-methylethylidene)-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of 5,8-Methanoquinoxaline,2,3,5,8-tetrahydro-9-(1-methylethylidene)-(9CI)

Chemical Property:

PSA：24.72000
LogP:0.90540

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 5,8-Methanoquinoxaline,2,3,5,8-tetrahydro-9-(1-methylethylidene)-(9CI)

There total 1 articles about 5,8-Methanoquinoxaline,2,3,5,8-tetrahydro-9-(1-methylethylidene)-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 60526-38-7
7-(1-methylethylidene)bicyclo[2.2.1]hept-5-ene-2,3-dione

: 107-15-3,85404-18-8
ethylenediamine

: 362050-14-4
9-(1-Methylethylidene)-2,3,5,8-tetrahydro-5,8-methanoquinoxaline

Guidance literature:: With toluene-4-sulfonic acid; In benzene; for 5h; Heating;
DOI:10.1039/b101330k

Reference yield:

: 362050-14-4
9-(1-Methylethylidene)-2,3,5,8-tetrahydro-5,8-methanoquinoxaline

: 1-(9-Isopropenyl-5,6,7,8-tetrahydro-5,8-methanoquinoxalin-9-yl)-4-phenyl-1,2,4-triazolidine-3,5-dione 1'-oxide

Guidance literature:: Multi-step reaction with 4 steps

1: 299 mg / nickel peroxide / benzene / 72 h / Heating

2: 28 percent / MCPBA / CH₂Cl₂ / 24 h / 20 °C

3: 96 percent / H₂ / 10percent Pd/C / ethyl acetate / 120 h / 20 °C

4: 97 percent / acetonitrile / 3 h / 20 °C

With nickel(IV) oxide; hydrogen; 3-chloro-benzenecarboperoxoic acid; 10percent Pd/C; In dichloromethane; ethyl acetate; acetonitrile; benzene;
DOI:10.1039/b101330k

Reference yield:

: 362050-14-4
9-(1-Methylethylidene)-2,3,5,8-tetrahydro-5,8-methanoquinoxaline

: 1-(9-Isopropenyl-5,8-dihydro-5,8-methanoquinoxalin-9-yl)-4-phenyl-1,2,4-triazolidine-3,5-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 299 mg / nickel peroxide / benzene / 72 h / Heating

2: 96 percent / acetonitrile / 3 h / 20 °C

With nickel(IV) oxide; In acetonitrile; benzene;
DOI:10.1039/b101330k