Pt(OB(Ph)OB(Ph)O)(dppe)

Base Information

• Chemical Name: Pt(OB(Ph)OB(Ph)O)(dppe)
• CAS No.: 883153-47-7
• Molecular Formula: C₃₈H₃₄B₂O₃P₂Pt
• Molecular Weight: 817.336
• Mol file: 883153-47-7.mol

Synonyms:Pt(OB(Ph)OB(Ph)O)(dppe)

Chemical Property of Pt(OB(Ph)OB(Ph)O)(dppe)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Pt(OB(Ph)OB(Ph)O)(dppe)

There total 1 articles about Pt(OB(Ph)OB(Ph)O)(dppe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum (29421-07-6) + phenylboronic acid (98-80-6) → Pt(OB(Ph)OB(Ph)O)(dppe) (883153-47-7)

Guidance literature:

With Ag₂O; H₂O; In tetrahydrofuran; byproducts: AgI; under N2 or Ar; to a THF/H2O (50 mL/1 mL) soln. of Pt-contg. compd. (1.0mmol) were added Ag2O (3.2 mmol) and B-contg. compd. (2.0 mmol) at room temp.; stirring for 3 h; the soln. was filtered and the resulting soln. was added dropwise to hexane; the complex was filtered off and dried under vac.; elem. anal.;

DOI:10.1021/om0509903

Reference yield:

Pt(OB(Ph)OB(Ph)O)(dppe) (883153-47-7) + phenylboronic acid (98-80-6) → (1,2-bis(diphenylphosphino)ethane)diphenylplatinum(II)

Guidance literature:

In tetrahydrofuran; benzene-d6; under N2 or Ar; to a THF/C6D6 soln. of Pt-contg. compd. (0.050 mmol) wasadded PhB(OH)2 (in 1:2 molar ratio); detd. by (31)P NMR spectra studies;

DOI:10.1021/om0509903

Reference yield:

Pt(OB(Ph)OB(Ph)O)(dppe) (883153-47-7) + 4-acetylphenylboronic acid (149104-90-5) → (1,2-bis(diphenylphosphino)ethane)diphenylplatinum(II) + Pt(C6H4COMe-4)(Ph)(dppe) (883153-51-3) + Pt(C6H4COMe-4)2(dppe) (883153-49-9)

Guidance literature:

In tetrahydrofuran; benzene-d6; under N2 or Ar; by a react. of Pt-contg. compd. with 4-MeCOC6H4B(OH)2 ina 1:2 molar ratio; detd. (31)P NMR spectra studies;

DOI:10.1021/om0509903

upstream raw materials:

cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

phenylboronic acid

Downstream raw materials:

Pt(C₆H₄COMe-4)(Ph)(dppe)

Pt(C₆H₄COMe-4)2(dppe)