cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

Base Information

Chemical Name:cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum
CAS No.:29421-07-6
Molecular Formula:C₂₆H₂₄I₂P₂Pt
Molecular Weight:847.313
Hs Code.:

Synonyms:cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

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Chemical Property of cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

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Technology Process of cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

There total 16 articles about cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 83095-83-4,14647-25-7
[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

: 7681-11-0
potassium iodide

: 29421-07-6
cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

Guidance literature:: In dichloromethane; to soln. of Pt compd. KI was added (0.15:0.78 molar ratio), stirred overnight; filtered, evapd., crystd. (CH2Cl2/Et2O), dried (vac.),;
DOI:10.1016/j.ica.2007.02.033

Reference yield: 80.0%

: PtSe₂N₂P(C₆H₅)2C₂H₄P(C₆H₅)2

: 29421-07-6
cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

: {Pt(Se₂N₂H)(1,2-bis(diphenylphosphino)ethane)}I

Guidance literature:: With iodine; In dichloromethane; byproducts: Se4N4; (N2,Ar), dry solvents; addn. of stoich. amts. of iodine to Pt compd. in CH2Cl2, stirring at room temp. (3 h), pptn. of Se4N4; evapn. to dryness; product mixt. not sepd., detn. by (31)P-NMR spectroscopy;

Reference yield: 75.0%

: 174967-15-8
cis-Pt(C_.tplbond.ruthenocenyl)(C₆H₄OMe-p)(1,2-bis(diphenylphosphino)ethane)

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 29421-07-6
cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

: 174967-14-7
(C₅H₅)Ru(C₅H₄C_.tplbond.CC₆H₄OMe-p)

: 174967-16-9
1,4-bis(ruthenocenyl)buta-1,3-diyne

Guidance literature:: In dichloromethane; benzene; byproducts: p-MeOC6H4I; N2-atmosphere; dropwise addn. of 1 equiv. I2 (in C6H6) to Ru-complex (inCH2Cl2/C6H6=2:5 v/v) with cooling in ice bath; evapn., chromy. (SiO2); elem. anal.;
DOI:10.1016/0022-328X(95)05815-7