cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

Base Information

• Chemical Name: cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum
• CAS No.: 29421-07-6
• Molecular Formula: C₂₆H₂₄I₂P₂Pt
• Molecular Weight: 847.313
• Mol file: 29421-07-6.mol

Synonyms:cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

Chemical Property of cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum

There total 16 articles about cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + potassium iodide (7681-11-0) → cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum (29421-07-6)

Guidance literature:

In dichloromethane; to soln. of Pt compd. KI was added (0.15:0.78 molar ratio), stirred overnight; filtered, evapd., crystd. (CH2Cl2/Et2O), dried (vac.),;

DOI:10.1016/j.ica.2007.02.033

Reference yield: 80.0%

PtSe2N2P(C6H5)2C2H4P(C6H5)2 → cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum (29421-07-6) + {Pt(Se2N2H)(1,2-bis(diphenylphosphino)ethane)}I

Guidance literature:

With iodine; In dichloromethane; byproducts: Se4N4; (N2,Ar), dry solvents; addn. of stoich. amts. of iodine to Pt compd. in CH2Cl2, stirring at room temp. (3 h), pptn. of Se4N4; evapn. to dryness; product mixt. not sepd., detn. by (31)P-NMR spectroscopy;

Reference yield: 75.0%

cis-Pt(C.tplbond.ruthenocenyl)(C6H4OMe-p)(1,2-bis(diphenylphosphino)ethane) (174967-15-8) + iodine (7553-56-2,12190-71-5,8031-47-8) → cis-[1,1'-(ethane-1,2-diyl)bis[1,1-diphenylphosphine-κP]]diiodoplatinum (29421-07-6) + (C5H5)Ru(C5H4C.tplbond.CC6H4OMe-p) (174967-14-7) + 1,4-bis(ruthenocenyl)buta-1,3-diyne (174967-16-9)

Guidance literature:

In dichloromethane; benzene; byproducts: p-MeOC6H4I; N2-atmosphere; dropwise addn. of 1 equiv. I2 (in C6H6) to Ru-complex (inCH2Cl2/C6H6=2:5 v/v) with cooling in ice bath; evapn., chromy. (SiO2); elem. anal.;

DOI:10.1016/0022-328X(95)05815-7

upstream raw materials:

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

potassium iodide

(1,5-cylooctadiene)di-iodoplatinum(II)

1,2-bis-(diphenylphosphino)ethane

Downstream raw materials:

selenium nitride

Pt(1,2-bis(diphenylphosphino)ethane)diphenylacetylene

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

{Pt((C₆H₅)2PCH₂CH₂P(C₆H₅)2)ICl}