methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside

Base Information

Chemical Name:methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside
CAS No.:1345664-84-7
Molecular Formula:C₅₀H₅₃O₁₀P
Molecular Weight:844.939
Hs Code.:

Synonyms:methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside

Suppliers and Price of methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside

There total 5 articles about methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1623-08-1
phosphoric acid dibenzyl ester

: 1345664-83-6
methyl 2,3,4,6-tetra-O-benzyl-D-glycero-α-D-gluco-heptopyranoside

: 1345664-84-7
methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside

Guidance literature:: With triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; toluene; at 20 ℃; for 15h; Inert atmosphere;
DOI:10.1002/chem.201100396

Reference yield:

: C₃₈H₅₄O₇Si

: 1345664-84-7
methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / N,N-dimethyl-formamide / 0 - 20 °C / Inert atmosphere

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C / Inert atmosphere

3: triethylamine; triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran; toluene / 15 h / 20 °C / Inert atmosphere

With tetrabutyl ammonium fluoride; sodium hydride; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; N,N-dimethyl-formamide; toluene; 3: Mitsunobu reaction;
DOI:10.1002/chem.201100396

Reference yield:

: 100-39-0
benzyl bromide

: 1345664-84-7
methyl 7-O-dibenzyloxyphosphoryl-2,3,4,6-tetra-O-benzyld-D-glycero-α-D-glucoheptopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / N,N-dimethyl-formamide / 0 - 20 °C / Inert atmosphere

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C / Inert atmosphere

3: triethylamine; triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran; toluene / 15 h / 20 °C / Inert atmosphere

With tetrabutyl ammonium fluoride; sodium hydride; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; N,N-dimethyl-formamide; toluene; 3: Mitsunobu reaction;
DOI:10.1002/chem.201100396