19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene

Base Information

Chemical Name:19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene
CAS No.:122475-99-4
Molecular Formula:C₂₃H₃₀O₅S
Molecular Weight:418.554
Hs Code.:

Synonyms:19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene

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Chemical Property of 19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene

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Technology Process of 19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene

There total 6 articles about 19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 108-98-5
thiophenol

: 122475-98-3
Toluene-4-sulfonic acid 19-methoxy-17-methyl-3,6,10,13-tetraoxa-bicyclo[13.3.1]nonadeca-1⁽¹⁸⁾,15⁽¹⁹⁾,16-trien-8-yl ester

: 122475-99-4
19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene

Guidance literature:: With sodium hydroxide; In ethanol; for 24h; Heating;

Reference yield:

: 6327-85-1
2,6-bis(hydroxymethyl)-4-methyl-anisole

: 122475-99-4
19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene

Guidance literature:: Multi-step reaction with 5 steps

1: 88 percent / PBr₃ / CH₂Cl₂ / 6 h / Ambient temperature

2: 65 percent / NaH / tetrahydrofuran / 2 h / Heating

3: 1.) O₃, 2.) NaBH₄ / 1.) EtOH, -78 deg C, 30 min, 2.) EtOH, RT, 12 h

4: 65 percent / pyridine / 24 h / 0 °C

5: 96 percent / NaOH / ethanol / 24 h / Heating

With pyridine; sodium hydroxide; sodium tetrahydroborate; phosphorus tribromide; sodium hydride; ozone; In tetrahydrofuran; ethanol; dichloromethane;

Reference yield:

: 28544-88-9
2,2'-(2-methylenepropane-1,3-diyldioxy)bisethanol

: 122475-99-4
19-methoxy-17-methyl-8-phenylthio-3,6,10,13-tetraoxabicyclo<13.3.1>nonadeca-1(19),15,17-triene

Guidance literature:: Multi-step reaction with 4 steps

1: 65 percent / NaH / tetrahydrofuran / 2 h / Heating

2: 1.) O₃, 2.) NaBH₄ / 1.) EtOH, -78 deg C, 30 min, 2.) EtOH, RT, 12 h

3: 65 percent / pyridine / 24 h / 0 °C

4: 96 percent / NaOH / ethanol / 24 h / Heating

With pyridine; sodium hydroxide; sodium tetrahydroborate; sodium hydride; ozone; In tetrahydrofuran; ethanol;