3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane

Base Information

• Chemical Name: 3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane
• CAS No.: 900179-82-0
• Molecular Formula: C₃₈H₃₉N₉O₁₂S₃
• Molecular Weight: 909.979
• Mol file: 900179-82-0.mol

Synonyms:3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane

Chemical Property of 3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane

There total 1 articles about 3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

11-(tert-butoxycarbonyl)-3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane → 3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane (900179-82-0)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 0 - 20 ℃;

DOI:10.1016/j.tet.2007.08.102

Reference yield: 93.0%

3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane (900179-82-0) + ethyl bromoacetate (105-36-2) → 11-(2-ethyloxy-2-oxoethyl)-3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane

Guidance literature:

With TEA; In tetrahydrofuran; for 5h; Heating;

DOI:10.1016/j.tet.2007.08.102

Reference yield: 92.0%

3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane (900179-82-0) + bromoacetic acid tert-butyl ester (5292-43-3) → 11-(2-tert-butoxy-2-oxoethyl)-3,7,15-tris(2-nitrobenzenesulfonyl)-1,5(2,6)-dipyridina-3,7,11,15-tetraazacyclohexadecaphane

Guidance literature:

With TEA; In tetrahydrofuran; for 5h; Heating;

DOI:10.1016/j.tet.2007.08.102