2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite

Base Information

Chemical Name:2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite
CAS No.:135589-28-5
Molecular Formula:C₂₃H₃₀O₅
Molecular Weight:386.488
Hs Code.:

Synonyms:2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite

Suppliers and Price of 2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite

There total 6 articles about 2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 98-88-4
benzoyl chloride

: 135589-27-4
2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-D-dulcite

: 135589-28-5
2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite

Guidance literature:: With pyridine; at -35 ℃; for 1h;
DOI:10.1007/BF00960425

Reference yield:

: 81076-93-9,101628-76-6,135681-50-4
(3R,4S,5S,6R)-4-Benzyloxy-2-methoxy-3,5,6-trimethyl-tetrahydro-pyran

: 135589-28-5
2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent / Raney nickel / methanol / 2 h / Heating

2: 81.2 percent / p-toluenesulfonic acid pyridinium salt (PPTS) / 4 h / Heating

3: 1.) NaH / 1.) DMF, 1 h, 2.) DMF, 12 h

4: 1.) t-BuOK, 2.) Hg(OAc)2 / 1.) DMSO, 100 deg C, 2 h, 2.) acetone, H₂O, 17 h

5: 70.5 percent / NaBH₄ / ethanol

6: 93 percent / pyridine / 1 h / -35 °C

With pyridine; sodium tetrahydroborate; potassium tert-butylate; mercury(II) diacetate; pyridinium p-toluenesulfonate; nickel; sodium hydride; In methanol; ethanol;
DOI:10.1007/BF00960425

Reference yield:

: 3720-33-0,118397-46-9,118455-41-7,119816-53-4,119816-55-6,119816-56-7,129446-67-9,135681-51-5
methyl-α,β-2,4,6-trideoxy-2,4-di-C-methyl-D-galactopyranoside

: 135589-28-5
2,4,6-trideoxy-2,4-di-C-methyl-3-O-(p-methoxybenzyl)-1-O-benzoyl-D-dulcite

Guidance literature:: Multi-step reaction with 5 steps

1: 81.2 percent / p-toluenesulfonic acid pyridinium salt (PPTS) / 4 h / Heating

2: 1.) NaH / 1.) DMF, 1 h, 2.) DMF, 12 h

3: 1.) t-BuOK, 2.) Hg(OAc)2 / 1.) DMSO, 100 deg C, 2 h, 2.) acetone, H₂O, 17 h

4: 70.5 percent / NaBH₄ / ethanol

5: 93 percent / pyridine / 1 h / -35 °C

With pyridine; sodium tetrahydroborate; potassium tert-butylate; mercury(II) diacetate; pyridinium p-toluenesulfonate; sodium hydride; In ethanol;
DOI:10.1007/BF00960425