N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide

Base Information

Chemical Name:N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide
CAS No.:1266490-71-4
Molecular Formula:C₇₆H₉₆N₄O₄Si₂
Molecular Weight:1185.79
Hs Code.:

Synonyms:N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide

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Chemical Property of N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide

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Technology Process of N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide

There total 4 articles about N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 1266490-63-4
N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-dichloro-1,4,5,8-tetracarboxylic acid naphthalenediimide

: 2380-36-1
3,5-di-tert-butylaniline

: 1266490-71-4
N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide

Guidance literature:: In N,N-dimethyl-formamide; at 110 ℃; for 16h; Inert atmosphere;
DOI:10.1002/ejoc.201001415

Reference yield:

: 89343-06-6
tris-iso-propylsilyl acetylene

: 1266490-71-4
N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide

Guidance literature:: Multi-step reaction with 3 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 5 h / 25 °C / Inert atmosphere

2: acetic anhydride / 0.5 h / 120 °C / Inert atmosphere

3: N,N-dimethyl-formamide / 16 h / 110 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; acetic anhydride; triethylamine; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Sonogashira coupling;
DOI:10.1002/ejoc.201001415

Reference yield:

: 540-37-4
p-aminoiodobenzene

: 1266490-71-4
N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-bis[(3,5-di-tert-butylphenyl)amine]-1,4,5,8-tetracarboxylic acid naphthalenediimide

Guidance literature:: Multi-step reaction with 3 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 5 h / 25 °C / Inert atmosphere

2: acetic anhydride / 0.5 h / 120 °C / Inert atmosphere

3: N,N-dimethyl-formamide / 16 h / 110 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; acetic anhydride; triethylamine; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Sonogashira coupling;
DOI:10.1002/ejoc.201001415