5-(4-methoxycarbonylphenyl)-10,15,20-tri-p-pentafluorophenylporphyrin

Base Information

• Chemical Name: 5-(4-methoxycarbonylphenyl)-10,15,20-tri-p-pentafluorophenylporphyrin
• CAS No.: 133833-23-5
• Molecular Formula: C₄₆H₁₇F₁₅N₄O₂
• Molecular Weight: 942.643
• Mol file: 133833-23-5.mol

Synonyms:5-(4-methoxycarbonylphenyl)-10,15,20-tri-p-pentafluorophenylporphyrin

Chemical Property of 5-(4-methoxycarbonylphenyl)-10,15,20-tri-p-pentafluorophenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-(4-methoxycarbonylphenyl)-10,15,20-tri-p-pentafluorophenylporphyrin

There total 10 articles about 5-(4-methoxycarbonylphenyl)-10,15,20-tri-p-pentafluorophenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

pyrrole (109-97-7,30604-81-0) + perfluorobenzaldehyde (653-37-2) + methyl 4-formylbenzoate (1571-08-0) → 5-(4'-carbomethoxyphenyl)-10,15,20-tris(pentafluorophenyl)porphyrin (133833-23-5)

Guidance literature:

pyrrole; perfluorobenzaldehyde; methyl 4-formylbenzoate; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere; Darkness;

With chloranil; In dichloromethane; for 12h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.5b01190

Reference yield: 19.0%

pyrrole (109-97-7,30604-81-0) + perfluorobenzaldehyde (653-37-2) + methyl 4-formylbenzoate (1571-08-0) → 5-(4-methoxycarbonylphenyl)-10,15,20-tri-p-pentafluorophenylporphyrin (133833-23-5)

Guidance literature:

pyrrole; perfluorobenzaldehyde; methyl 4-formylbenzoate; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 2h;

With chloranil; In dichloromethane; at 20 ℃; for 1.5h; Further stages.;

DOI:10.1021/ja0752639

Reference yield: 16.0%

perfluorobenzaldehyde (653-37-2) + 5-(pentafluorophenyl)dipyrromethane (167482-91-9) + methyl 4-formylbenzoate (1571-08-0) → 5-(4-methoxycarbonylphenyl)-10,15,20-tri-p-pentafluorophenylporphyrin (133833-23-5)

Guidance literature:

perfluorobenzaldehyde; 5-(pentafluorophenyl)dipyrromethane; methyl 4-formylbenzoate; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 3h;

With chloranil; In dichloromethane; at 20 ℃; for 1h; Further stages.;

DOI:10.1002/(SICI)1521-3765(20000103)6:1<33::AID-CHEM33>3.0.CO;2-7

upstream raw materials:

pyrrole

perfluorobenzaldehyde

methyl 4-formylbenzoate

5-(pentafluorophenyl)dipyrromethane

Downstream raw materials:

5-(4-carboxyphenyl)-10,15,20-tris(pentafluorophenyl)porphyrin

4-((5Z,10Z,14Z,19Z)-10,15,20-Tris-pentafluorophenyl-porphyrin-5-yl)-benzoyl chloride

5-(4-carboxyphenyl)-10,15,20-tri-(pentafluorophenyl)porphyrin