Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester

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Chemical Name:Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester
CAS No.:920750-02-3
Molecular Formula:C₂₄H₃₇NOS
Molecular Weight:387.63
Hs Code.:

Synonyms:Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester

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Chemical Property of Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester

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Technology Process of Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester

There total 3 articles about Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 868744-82-5
(R,E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)-4,4-dimethylpent-2-en-1-ol

: 103-72-0
phenyl isothiocyanate

: 920750-02-3
Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester

Guidance literature:: (R,E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)-4,4-dimethylpent-2-en-1-ol; With sodium hydride; In tetrahydrofuran; at 0 ℃; for 1h;

phenyl isothiocyanate; In tetrahydrofuran; for 3h; Heating;

With pyridinium p-toluenesulfonate; In tetrahydrofuran; Heating;
DOI:10.1016/j.jorganchem.2006.07.028

Reference yield:

: 61382-45-4
(E)-1-iodo-3,3-dimethyl-1-butene

: 920750-02-3
Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: t-BuLi / diethyl ether

1.2: AlMe₃ / diethyl ether

2.1: NaH / tetrahydrofuran / 1 h / 0 °C

2.2: tetrahydrofuran / 3 h / Heating

2.3: 96 percent / pyridinium p-toluenesulfonate / tetrahydrofuran / 2 h / Heating

With tert.-butyl lithium; sodium hydride; In tetrahydrofuran; diethyl ether;
DOI:10.1139/V07-091

Reference yield:

: 80434-59-9,485843-44-5,796865-68-4
(1R,2S,5R)-2-isopropyl-5-methylcyclohexanecarboxaldehyde

: 920750-02-3
Phenyl-thiocarbamic acid S-[(E)-(S)-1-tert-butyl-3-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-allyl] ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: t-BuLi / diethyl ether

1.2: AlMe₃ / diethyl ether

2.1: NaH / tetrahydrofuran / 1 h / 0 °C

2.2: tetrahydrofuran / 3 h / Heating

2.3: 96 percent / pyridinium p-toluenesulfonate / tetrahydrofuran / 2 h / Heating

With tert.-butyl lithium; sodium hydride; In tetrahydrofuran; diethyl ether;
DOI:10.1139/V07-091