[(4,4′-dinitro-2,2′-bipyridine)Pt(CH₂CH₂Ph)(η²-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)₄]

Base Information

• Chemical Name: [(4,4′-dinitro-2,2′-bipyridine)Pt(CH₂CH₂Ph)(η²-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)₄]
• CAS No.: 1430851-49-2
• Molecular Formula: C₂₀H₁₉N₄O₄Pt*C₃₂H₁₂BF₂₄
• Molecular Weight: 1437.7

Synonyms:[(4,4′-dinitro-2,2′-bipyridine)Pt(CH₂CH₂Ph)(η²-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)₄]

Chemical Property of [(4,4′-dinitro-2,2′-bipyridine)Pt(CH₂CH₂Ph)(η²-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)₄]

Chemical Property:

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Technology Process of [(4,4′-dinitro-2,2′-bipyridine)Pt(CH₂CH₂Ph)(η²-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)₄]

There total 1 articles about [(4,4′-dinitro-2,2′-bipyridine)Pt(CH₂CH₂Ph)(η²-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

ethene (74-85-1) + [(4,4′-dinitro-2,2′-bipyridine)Pt(Ph)(THF)][B(3,5-bis(trifluoromethyl)phenyl)4] (1430851-41-4) → [(4,4′-dinitro-2,2′-bipyridine)Pt(CH2CH2Ph)(η2-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)4] (1430851-49-2)

Guidance literature:

In dichloromethane; for 12h; under 2250.23 Torr; Autoclave;

DOI:10.1021/om400306w

Reference yield:

[(4,4′-dinitro-2,2′-bipyridine)Pt(CH2CH2Ph)(η2-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)4] (1430851-49-2) → ethylbenzene (100-41-4,27536-89-6)

Guidance literature:

In benzene; at 100 ℃; for 4h; Inert atmosphere;

DOI:10.1021/om400306w

Reference yield:

ethene (74-85-1) + [(4,4′-dinitro-2,2′-bipyridine)Pt(CH2CH2Ph)(η2-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)4] (1430851-49-2) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + [(4,4′-dinitro-2,2′-bipyridine)Pt(CH2CH5)(η2-ethylene)][B(3,5-bis(trifluoromethyl)phenyl)4]

Guidance literature:

In nitromethane-d3; at 45 ℃; under 2250.23 Torr; Kinetics;

DOI:10.1021/om400306w

upstream raw materials:

ethene

[(4,4′-dinitro-2,2′-bipyridine)Pt(Ph)(THF)][B(3,5-bis(trifluoromethyl)phenyl)₄]

Downstream raw materials:

styrene

ethylbenzene

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