(+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol

Base Information

Chemical Name:(+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol
CAS No.:736140-48-0
Molecular Formula:C₂₅H₃₃NO₄
Molecular Weight:411.541
Hs Code.:

Synonyms:(+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol

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Chemical Property of (+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol

Chemical Property:

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Technology Process of (+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol

There total 1 articles about (+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1779-49-3
Methyltriphenylphosphonium bromide

: 97682-96-7,99726-01-9,127505-65-1
(2S)-1-(phenylmethoxy)but-3-en-2-ylamine

: 143521-62-4
5-(4-methoxyphenyl)methoxy-2Z-penten-1-ol

: 736140-48-0
(+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol

: (+)-1-(4-methoxyphenyl)methoxy-4R-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3R-ol

Guidance literature:: Multistep reaction.;
DOI:10.1016/j.tet.2004.05.010

Reference yield: 94.0%

: 32315-10-9
bis(trichloromethyl) carbonate

: 736140-48-0
(+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol

: 736140-49-1
(+)-4S-ethenyl-5S-[2-(4-methoxyphenyl)methoxy]ethyl-3-(1S-phenylmethoxymethyl-2-propenyl)-1,3-oxazolidin-2-one

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; for 2.5h;
DOI:10.1016/j.tet.2004.05.010

Reference yield:

: 736140-48-0
(+)-1-(4-methoxyphenyl)methoxy-(4S)-[(1S-phenylmethoxymethyl)-2-propenylamino]-5-hexen-3S-ol

: 736140-53-7
(-)-(1S,5R,6R,7S,7aS)-6,7-diacetoxy-1-(2-hydroxy)ethyl-5-(phenylmethoxy)methyl-5,6,7,7a-tetrahydro-1H,3H-pyrrolo[1,2-c]oxazol-3-one

Guidance literature:: Multi-step reaction with 5 steps

1: 94 percent / Et₃N / CH₂Cl₂ / 2.5 h / 0 °C

2: 97 percent / benzylidenebis(tricyclohexylphosphine)ruthenium dichloride / CH₂Cl₂ / 42 h / Heating

3: 85 percent / 4-morpholine N-oxide; K₂OsO₄*2H₂O / acetone; H₂O / 21 h / 20 °C

4: 84 percent / pyridine / 23 h / 20 °C

5: 65 percent / 2,3-dichloro-5,6-dicyanobenzoquinone / CH₂Cl₂; H₂O / 5.5 h / 20 °C

With pyridine; potassium osmate(VI); 4-methylmorpholine N-oxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; Grubbs catalyst first generation; In dichloromethane; water; acetone;
DOI:10.1016/j.tet.2004.05.010