(1R,3R,5R,7R,9S,14R)-7-Phenyl-3-trimethylsilylmethyl-2,6,8,11,13-pentaoxatricyclo<9.3.0.0^9,14>tetradecane

Base Information

• Chemical Name: (1R,3R,5R,7R,9S,14R)-7-Phenyl-3-trimethylsilylmethyl-2,6,8,11,13-pentaoxatricyclo<9.3.0.0^9,14>tetradecane
• CAS No.: 143573-31-3
• Molecular Formula: C₁₉H₂₈O₅Si
• Molecular Weight: 364.514

Synonyms:(1R,3R,5R,7R,9S,14R)-7-Phenyl-3-trimethylsilylmethyl-2,6,8,11,13-pentaoxatricyclo<9.3.0.0^9,14>tetradecane

Chemical Property of (1R,3R,5R,7R,9S,14R)-7-Phenyl-3-trimethylsilylmethyl-2,6,8,11,13-pentaoxatricyclo<9.3.0.0^9,14>tetradecane

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Technology Process of (1R,3R,5R,7R,9S,14R)-7-Phenyl-3-trimethylsilylmethyl-2,6,8,11,13-pentaoxatricyclo<9.3.0.0^9,14>tetradecane

There total 1 articles about (1R,3R,5R,7R,9S,14R)-7-Phenyl-3-trimethylsilylmethyl-2,6,8,11,13-pentaoxatricyclo<9.3.0.0^9,14>tetradecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1S,3S,5S,6R)-3-Phenyl-2,4,7,9-tetraoxabicyclo<4.4.0>decan-5-carboxaldehyde (143573-24-4) + allyl-trimethyl-silane (762-72-1) → (1S,3S,5R,6R)-5-<(1R)-1-Hydroxy-3-butenyl>-3-phenyl-2,4,7,9-tetraoxabicyclo<4.4.0>decane (143573-32-4) + (1R,3R,5R,7R,9S,14R)-7-Phenyl-3-trimethylsilylmethyl-2,6,8,11,13-pentaoxatricyclo<9.3.0.09,14>tetradecane (143573-31-3)

Guidance literature:

With boron trifluoride diethyl etherate; Yield given. Multistep reaction. Yields of byproduct given; 1) CH₂Cl₂, -78 deg C, 15 min;

DOI:10.1016/S0040-4020(01)89027-X

Reference yield: 81.0%

(1R,3R,5R,7R,9S,14R)-7-Phenyl-3-trimethylsilylmethyl-2,6,8,11,13-pentaoxatricyclo<9.3.0.09,14>tetradecane (143573-31-3) → (1S,3S,5R,6R)-5-<(1R)-1-Hydroxy-3-butenyl>-3-phenyl-2,4,7,9-tetraoxabicyclo<4.4.0>decane (143573-32-4)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; -78 deg C to - 20 deg C then 1 h;

DOI:10.1016/S0040-4020(01)89027-X

upstream raw materials:

(1S,3S,5S,6R)-3-Phenyl-2,4,7,9-tetraoxabicyclo<4.4.0>decan-5-carboxaldehyde

allyl-trimethyl-silane

Downstream raw materials:

(1S,3S,5R,6R)-5-<(1R)-1-Hydroxy-3-butenyl>-3-phenyl-2,4,7,9-tetraoxabicyclo<4.4.0>decane

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