(n-Bu₄N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))]

Base Information

• Chemical Name: (n-Bu₄N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))]
• CAS No.: 1191408-28-2
• Molecular Formula: C₁₆H₃₆N*C₂₉H₁₇N₄O₆Ru
• Molecular Weight: 861.016

Synonyms:(n-Bu₄N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))]

Chemical Property of (n-Bu₄N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))]

Chemical Property:

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Technology Process of (n-Bu₄N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))]

There total 1 articles about (n-Bu₄N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetra-n-butylammonium hydroxide + Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine) (1191408-26-0) → (n-Bu4N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))] (1191408-28-2)

Guidance literature:

In N,N-dimethyl-formamide; elem. anal.;

DOI:10.1021/ja902942g

Reference yield:

(n-Bu4N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))] (1191408-28-2) → Ru(III)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine-4'-(4-phenylcarboxylate)) (1415722-09-6)

Guidance literature:

With [(p-BrC₆H₄)3N)][B(C₆F₅)4]; In acetonitrile; pptd. with CH2Cl2;

DOI:10.1021/ja902942g

upstream raw materials:

Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine)

Downstream raw materials:

Ru(III)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine-4'-(4-phenylcarboxylate))

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