(2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal

Base Information

Chemical Name:(2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal
CAS No.:186895-58-9
Molecular Formula:C₂₃H₃₈O₂Si
Molecular Weight:374.639
Hs Code.:

Synonyms:(2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal

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Technology Process of (2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal

There total 12 articles about (2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 186895-57-8
(2RS,3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-1,2-dihydroxy-3,5,7-trimethyl-9-phenyl-5-nonene

: 186895-58-9
(2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal

Guidance literature:: With lead(IV) acetate; In dichloromethane; at 0 ℃;
DOI:10.1021/ol990944x

Reference yield:

: 186895-56-7
(3R,4R,5E,7S)-4-(tert-butyldimethylsilyloxy)-3,5,7-trimethyl-9-phenyl-1,5-nonadiene

: 186895-58-9
(2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / AD-mix / 2-methyl-propan-2-ol; H₂O

2: 99 percent / Pb(OAc)4 / CH₂Cl₂ / 0 °C

With lead(IV) acetate; In dichloromethane; water; tert-butyl alcohol;
DOI:10.1021/ol990944x

Reference yield:

: 186895-54-5
(2E,4S)-2,4-dimethyl-6-phenyl-2-hexen-1-al

: 186895-58-9
(2S,3R,4E,6S)-3-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-8-phenyl-4-octanal

Guidance literature:: Multi-step reaction with 5 steps

1: 53 percent / petroleum ether / 25 °C

2: 72 percent / lutidine / CH₂Cl₂ / 0 °C

3: 99 percent / lithium / liquid ammonia / -78 °C

4: 99 percent / AD-mix / 2-methyl-propan-2-ol; H₂O

5: 99 percent / Pb(OAc)4 / CH₂Cl₂ / 0 °C

With lead(IV) acetate; lutidine; lithium; In dichloromethane; ammonia; water; Petroleum ether; tert-butyl alcohol;
DOI:10.1021/ol990944x