(TPP)In(C₂H₅)

Base Information

• Chemical Name: (TPP)In(C₂H₅)
• CAS No.: 63036-65-7
• Molecular Formula: C₄₆H₃₃InN₄
• Molecular Weight: 756.615
• Mol file: 63036-65-7.mol

Synonyms:(TPP)In(C₂H₅)

Chemical Property of (TPP)In(C₂H₅)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (TPP)In(C₂H₅)

There total 1 articles about (TPP)In(C₂H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

ethylmagnesium iodide (10467-10-4) + (5,10,15,20-tetraphenylporphyrinato)(chloro)indium(III) (36522-28-8,63128-70-1) → (TPP)In(C2H5) (63036-65-7)

Guidance literature:

In diethyl ether; (N2); In-complex was added to a soln. of organic compound; stirred for 2 h; cold water was added; extracted with benzene; chromy.; elem. anal.;

DOI:10.1021/j100408a031

Reference yield: 98.0%

(TPP)In(C2H5) (63036-65-7) → (5,10,15,20-tetraphenylporphyrinato)(chloro)indium(III) (36522-28-8,63128-70-1)

Guidance literature:

With hydrogenchloride; air; In benzene; Irradiation (UV/VIS); irradiation of aerated soln. by sunlight for 2 days; evapn. of the benzene; residue was dissolved in an ethanol soln. of HCl; identification by IR and UV;

DOI:10.1021/j100408a031

Reference yield:

(TPP)In(C2H5) (63036-65-7) → (TPP)}In(1+)

Guidance literature:

With 7,7',8,8'-tetracyanoquinodimethane; In 2-methyltetrahydrofuran; byproducts: tetracyanoquinodimethane(1-), C2H5; Irradiation (UV/VIS); investigation of photochemical react. of ethylindium(III) porphyrin in presence of tetracyanoquinodimethane in 2-methyltetrahydrofuran by steady light photolysis and laser flash photolysis;; not isolated, react. is monitored by spectrophotometry and ESR;; Kinetics;

DOI:10.1021/ic00273a020

upstream raw materials:

ethylmagnesium iodide

(5,10,15,20-tetraphenylporphyrinato)(chloro)indium(III)

Downstream raw materials:

(TPP)In radical

(5,10,15,20-tetraphenylporphyrinato)(chloro)indium(III)