(S)-phenyl(1-phenylethyl)selane

Base Information

• Chemical Name: (S)-phenyl(1-phenylethyl)selane
• CAS No.: 1415088-77-5
• Molecular Formula: C₁₄H₁₄Se
• Molecular Weight: 261.225
• Mol file: 1415088-77-5.mol

Synonyms:(S)-phenyl(1-phenylethyl)selane

Chemical Property of (S)-phenyl(1-phenylethyl)selane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-phenyl(1-phenylethyl)selane

There total 12 articles about (S)-phenyl(1-phenylethyl)selane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

phenyl selenocyanate (2179-79-5) + (R)-1-phenylethanol (1517-69-7) → (S)-phenyl(1-phenylethyl)selane (1415088-77-5)

Guidance literature:

With tributylphosphine; In tetrahydrofuran; at 20 ℃; for 16h;

DOI:10.1016/j.tet.2012.09.087 DOI:10.1016/j.tet.2012.09.087

Reference yield:

1-phenylethyl phenyl selenide (39192-26-2) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + (S)-phenyl(1-phenylethyl)selane (1415088-77-5) + (R)-phenyl(1-phenylethyl)selane (819850-07-2)

Guidance literature:

With sodium phosphite; Thermobifida fusca recombinant phenylacetone monooxygenase; phosphite dehydrogenase; NADP+; In dimethyl sulfoxide; at 30 ℃; for 5h; pH=7.5; Concentration; Reagent/catalyst; Time; enantioselective reaction; Catalytic behavior; Enzymatic reaction;

DOI:10.1016/j.tet.2012.09.087 DOI:10.1016/j.tet.2012.09.087

Reference yield:

1-phenylethyl phenyl selenide (39192-26-2) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + (S)-phenyl(1-phenylethyl)selane (1415088-77-5)

Guidance literature:

With sodium phosphite; Thermobifida fusca recombinant phenylacetone monooxygenase; phosphite dehydrogenase; NADP+; In dimethyl sulfoxide; at 30 ℃; for 5h; pH=7.5; enantioselective reaction; Enzymatic reaction;

DOI:10.1016/j.tet.2012.09.087 DOI:10.1016/j.tet.2012.09.087

upstream raw materials:

1-phenylethyl phenyl selenide

1-Phenylethanol

phenyl selenocyanate

(R)-1-phenylethanol