1-Butyl-3-methylimidazolium acetate

Base Information

• Chemical Name: 1-Butyl-3-methylimidazolium acetate
• CAS No.: 284049-75-8
• Molecular Formula: C10H18N2O2
• Molecular Weight: 198.265
• European Community (EC) Number: 801-336-8
• DSSTox Substance ID: DTXSID20580410
• Mol file: 284049-75-8.mol

Synonyms:1-butyl-3-methylimidazolium;1-butyl-3-methylimidazolium acetate;1-butyl-3-methylimidazolium dodecyl sulfate;1-butyl-3-methylimidazolium trifluoroacetate;C4MIM compound;Pbmim compound

Chemical Property of 1-Butyl-3-methylimidazolium acetate

Chemical Property:

• Melting Point: -20 °C
• Flash Point: 153 °C
• PSA: 48.94000
• Density: 1.05g/ml
• LogP: -0.13110
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 198.136827821
• Heavy Atom Count: 14
• Complexity: 119

Purity/Quality:

97% ^*data from raw suppliers

1-Butyl-3-methylimidazolium acetate, 95%, [BMIM]acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN1C=C[N+](=C1)C.CC(=O)[O-]
• Uses: 1-Butyl-3-methylimidazolium acetate may be used to effectively capture CO2 from post-combustion flue gas. It may be used in the preparation of 1-butyl-3-methylimidazolium-2-carboxylate via carboxylation with CO2.

Technology Process of 1-Butyl-3-methylimidazolium acetate

There total 31 articles about 1-Butyl-3-methylimidazolium acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-butyl-3-methyl-1H-imidazol-3-ium methylcarbonate (916850-37-8) + acetic acid (64-19-7,77671-22-8) → 3-butyl-1-methylimidazolium acetate (284049-75-8)

Guidance literature:

In methanol; at 0 - 20 ℃; for 1h;

DOI:10.1016/j.electacta.2021.137865

Reference yield: 100.0%

ammonium acetate (631-61-8,92206-38-7) + 1-methyl-3-(n-butyl)imidazolium iodide (65039-05-6) → 3-butyl-1-methylimidazolium acetate (284049-75-8)

Guidance literature:

ammonium acetate; With Amberlyst A-26 (OH^- form); In water; at 20 ℃;

1-methyl-3-(n-butyl)imidazolium iodide; In methanol;

DOI:10.3390/molecules17044007

Reference yield: 96.0%

1-butyl-3-methylimidazolium chloride (79917-90-1) → 3-butyl-1-methylimidazolium acetate (284049-75-8)

Guidance literature:

With ammonium acetate; In acetone; at 20 ℃; for 24h;

DOI:10.1039/c1nj20739c

upstream raw materials:

sodium acetate

1-Butylimidazole

dimethylsulfite

acetic acid

Downstream raw materials:

n-octyl acetate

3-phenylpropyl acetate

4-phenylbut-2-yl acetate

2-Octyl acetate