Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester

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Chemical Name:Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester
CAS No.:202916-64-1
Molecular Formula:C₃₃H₄₆O₇
Molecular Weight:554.724
Hs Code.:

Synonyms:Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester

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Chemical Property of Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester

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Technology Process of Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester

There total 9 articles about Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 104227-38-5
methyl 6-(dimethoxyphosphoryl)-5-oxohexanoate

: 202916-63-0
Benzoic acid (1S,2R,3R,4R)-3-formyl-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester

: 202916-64-1
Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester

Guidance literature:: With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In dichloromethane; water; Ambient temperature;

Reference yield:

: 110-87-2
3,4-dihydro-2H-pyran

: 202916-64-1
Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 92 percent / p-TsOH / CH₂Cl₂ / 0.5 h / 0 °C

2: iBu₂AlH / CH₂Cl₂; hexane / 1 h / -78 °C

3: benzene / 3 h

4: 81 percent / pyridine / 0.75 h / 0 °C

5: 80 percent / Bu₄NF / tetrahydrofuran / 2 h / Ambient temperature

6: 1.67 g / CrO₃, Py / CH₂Cl₂

7: 68 percent / NaOH, triethylbenzylammonium chloride / H₂O; CH₂Cl₂ / Ambient temperature

With pyridine; chromium(VI) oxide; sodium hydroxide; tetrabutyl ammonium fluoride; N-benzyl-N,N,N-triethylammonium chloride; diisobutylaluminium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; hexane; dichloromethane; water; benzene;

Reference yield:

: 32233-40-2
(3aR,4S,5R,6aS)-5-hydroxy-4-(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one

: 202916-64-1
Benzoic acid (1S,2R,3R,4R)-3-((E)-6-methoxycarbonyl-3-oxo-hex-1-enyl)-2-((Z)-oct-2-enyl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 84 percent / imidazole / dimethylformamide / 1 h / 0 °C

2: 92 percent / p-TsOH / CH₂Cl₂ / 0.5 h / 0 °C

3: iBu₂AlH / CH₂Cl₂; hexane / 1 h / -78 °C

4: benzene / 3 h

5: 81 percent / pyridine / 0.75 h / 0 °C

6: 80 percent / Bu₄NF / tetrahydrofuran / 2 h / Ambient temperature

7: 1.67 g / CrO₃, Py / CH₂Cl₂

8: 68 percent / NaOH, triethylbenzylammonium chloride / H₂O; CH₂Cl₂ / Ambient temperature

With pyridine; 1H-imidazole; chromium(VI) oxide; sodium hydroxide; tetrabutyl ammonium fluoride; N-benzyl-N,N,N-triethylammonium chloride; diisobutylaluminium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; hexane; dichloromethane; water; N,N-dimethyl-formamide; benzene;