1-[(Z)-1-(Trimethylsilyl)-2-phenylethenylthio]-2-propanone

Base Information

Chemical Name:1-[(Z)-1-(Trimethylsilyl)-2-phenylethenylthio]-2-propanone
CAS No.:294860-73-4
Molecular Formula:C₁₄H₂₀OSSi
Molecular Weight:264.464
Hs Code.:
DSSTox Substance ID:DTXSID501180723
Nikkaji Number:J1.355.433A

Synonyms:DTXSID501180723;1-[(Z)-1-(Trimethylsilyl)-2-phenylethenylthio]-2-propanone;1-[[(1Z)-2-Phenyl-1-(trimethylsilyl)ethenyl]thio]-2-propanone;294860-73-4

Suppliers and Price of 1-[(Z)-1-(Trimethylsilyl)-2-phenylethenylthio]-2-propanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-[(Z)-1-(Trimethylsilyl)-2-phenylethenylthio]-2-propanone

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:264.10041297
Heavy Atom Count:17
Complexity:285

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=O)CSC(=CC1=CC=CC=C1)[Si](C)(C)C
Isomeric SMILES:CC(=O)CS/C(=C\C1=CC=CC=C1)/[Si](C)(C)C

Technology Process of 1-[(Z)-1-(Trimethylsilyl)-2-phenylethenylthio]-2-propanone

There total 1 articles about 1-[(Z)-1-(Trimethylsilyl)-2-phenylethenylthio]-2-propanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 78-95-5
chloroacetone

: 185844-35-3
(Z)-2-phenyl-1-trimethylsilylethenenethiol

: 294860-73-4
(Z)-1-[(2-phenyl-1-trimethylsilylvinyl)sulfanyl]propan-2-one

Guidance literature:: With potassium carbonate; In acetone; at 20 ℃;
DOI:10.1002/1099-0690(200007)2000:13<2391::AID-EJOC2391>3.0.CO;2-M

Reference yield: 86.0%

: 294860-73-4
(Z)-1-[(2-phenyl-1-trimethylsilylvinyl)sulfanyl]propan-2-one

: 4-phenyl-2-(phenylmethylidene)-1,3-dithiol

: 294860-99-4
3-methyl-2-[(Z)-phenylmethylidene]-3-thietanol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 66 ℃;
DOI:10.1002/1099-0690(200007)2000:13<2391::AID-EJOC2391>3.0.CO;2-M

Reference yield:

: 294860-73-4
(Z)-1-[(2-phenyl-1-trimethylsilylvinyl)sulfanyl]propan-2-one

: 3-hydroxy-3-methyl-2-[(Z)-phenylmethylidene]-1λ⁶-thietane-1,1-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / TBAF / tetrahydrofuran / 66 °C

2: 90 percent / oxone / methanol; H₂O / 5 h / 20 °C

With Oxone; tetrabutyl ammonium fluoride; In tetrahydrofuran; methanol; water; 1: Cyclization / 2: Oxidation;
DOI:10.1002/1099-0690(200007)2000:13<2391::AID-EJOC2391>3.0.CO;2-M