185844-35-3

Basic information

• Product Name: (Z)-2-phenyl-1-trimethylsilylethenenethiol
• Synonyms: (Z)-2-phenyl-1-trimethylsilylethenenethiol
• CAS NO: 185844-35-3
• Molecular Weight: 208.4
• Mol File: 185844-35-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-2-phenyl-1-trimethylsilylethenenethiol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-phenyl-1-trimethylsilylethenenethiol(185844-35-3)
• EPA Substance Registry System: (Z)-2-phenyl-1-trimethylsilylethenenethiol(185844-35-3)

Safety Data

• Hazardous Substances Data: 185844-35-3(Hazardous Substances Data)

Upstream product

• 56583-94-9 (phenylacetyl)trimethylsilane 

Downstream Products

• 294860-91-6 5-[(Z)-(2-phenyl-1-trimethylsilylvinyl)sulfanyl]pentan-2-one 
• 185844-50-2 ((Z)-1-Methanesulfonyl-2-phenyl-vinyl)-trimethyl-silane 
• 125065-60-3 Ethyl <(Z)-(2-phenylvinyl)sulfanyl>acetate 
• 136365-87-2 (E)-1-ethyl-2-phenylethenyltrimethylsilane 
• 57266-92-9 (E)-1-methyl-2-phenylethenyltrimethylsilane 
• 13294-33-2 (Z)-styryl benzylsulfide 
• 37630-43-6 (Z)-1-(methylsulfonyl)-2-phenylethene 
• 15436-11-0 (E)-methyl styryl sulfone 
• 19372-00-0 1-(trimethylsilyl)-2-phenylethene 
• 42442-59-1 (Z)-1-(Allylthio)-2-phenylethylene 
• 35822-50-5 (Z)-methyl(styryl)sulfane 
• 294861-22-6 3-methyl-2-[(Z)-2-phenylmethylidene]tetrahydro-2H-thiopyran-3-yl acetate 
• 294861-05-5 3-methyl-2-[(Z)-2-phenylmethylidene]tetrahydro-2H-thiopyran-3-ol 

Relevant articles and documents

Chemistry of silyl thioketones. Part 10. Synthesis and reactivity of α-silyl vinyl sulfldes

Aliphatic silyl thioketones containing an α-hydrogen atom undergo enethiolization to Z-α-silyl enethiols 2. Compounds 2 react with a variety of halides R3X to give open-chain α-silyl vinyl sulfides 3. Protiodesilylation of 3 was achieved upon treatment with fluoride ion to give vinyl sulfides 4. Reaction of 3 with Grignard reagents, in the presence of an appropriate nickel catalyst, results in a series of vinylsilanes 5 with a specific geometry.