anilinium

Base Information

• Chemical Name: anilinium
• CAS No.: 17032-11-0
• Molecular Formula: C₆H₈N
• Molecular Weight: 94.1362
• Mol file: 17032-11-0.mol

Synonyms:anilinium

Chemical Property of anilinium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of anilinium

There total 22 articles about anilinium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

protonated trimethyl phosphate (497956-56-6) + aniline (62-53-3) → trimethyl phosphite (512-56-1) + anilinium (17032-11-0)

Guidance literature:

Thermodynamic data; Equilibrium constant; Ambient temperature; Δ G, Δ H;

DOI:10.1021/ja00524a016

Reference yield:

benzene cation (71-43-2) + aniline (62-53-3) → phenyl radical (2396-01-2) + anilinium (17032-11-0) + phenylnitrenium ion (62-53-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In gas; at 200 ℃; Mechanism; charge transfer vs. proton transfer; further amines;

DOI:10.1002/oms.1210251003

Reference yield:

aniline (62-53-3) → anilinium (17032-11-0)

Guidance literature:

With 3-chloro-aniline; protonated form; at 326.9 ℃; Thermodynamic data; Equilibrium constant; in gas phase; ΔG_PT, ΔE_B(N_1s), oteher substituted anilines, temperatures;

DOI:10.1021/ja00411a004

upstream raw materials:

benzoic acid methyl ester

bromobenzene

iodobenzene

benzoyl cation

Downstream raw materials:

benzenediazonium

p-nitroanilinium ion

m-Nitroanilinium ion

p-nitrobenzenediazonium

Refernces

• 1、 Izutsu, Kosuke,Nakamura, Toshio,Takizawa, Katsumi,Takeda, Akihiko. "Calorimetric Determination of Thermodynamic Parameters for the Dissociations of Acids in Dipolar Aprotic Solvents". . p. 455 - 458. Retrieved 1985.
• 2、 Maeyama, Toshihiko,Mikami, Naohiko. "Nucleophilic Substitution within the Photoionized van der Waals Complex: Generation of C6H5NH3(1+) from C6H5Cl-NH3". . p. 7238 - 7239. Retrieved 1988.
• 3、 Peschke, Michael,Blades, Arthur,Kebarle, Paul. "Charged states of proteins. Reactions of doubly protonated alkyldiamines with NH3: Solvation or deprotonation. Extension of two proton cases to multiply protonated globular proteins observed in the gas phase". . p. 11519 - 11530. Retrieved 2007/10/03.