Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

Base Information

Chemical Name:Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate
CAS No.:111436-93-2
Molecular Formula:C₅₈H₇₄O₁₂Si
Molecular Weight:991.304
Hs Code.:

Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'-<cyclohexylidenebis(oxy)>-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

Synonyms:Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

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Chemical Property of Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

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Technology Process of Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

There total 1 articles about Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3587-60-8
Benzyloxymethyl chloride

: 111436-92-1
methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate

: 111436-93-2
Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

Guidance literature:: With sodium hydride; Yield given. Multistep reaction; THF, DMF, 1.) room temp, 20 min, 2.) 1 h;
DOI:10.1021/ja00190a036

Reference yield:

: 111436-93-2
Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

: 1,6,8-Tris-benzyloxymethoxy-3-[(2R,3S,4R)-4-(tert-butyl-dimethyl-silanyloxy)-2-carboxymethyl-3-methoxy-4-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-butyl]-naphthalene-2-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) 0.5 M 9-BBN, 2.) 3 M aq. NaOH, 30percent H₂O₂ / 1.) THF, 23 deg C, 2 h, 2.) 23 deg C, 2 h

2: 90 percent / DMSO, oxalyl chloride / CH₂Cl₂ / 0.17 h / -78 °C

3: 1 M aq. KMnO₄, 1.25 M aq. KH₂PO₄ / 2-methyl-propan-2-ol; dimethylformamide / 0.5 h

With sodium hydroxide; potassium permanganate; potassium dihydrogenphosphate; 9-borabicyclo[3.3.1]nonane dimer; oxalyl dichloride; dihydrogen peroxide; dimethyl sulfoxide; In dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1021/ja00190a036

Reference yield:

: 111436-93-2
Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate

: 120264-60-0,120329-91-1
6,8,9-Tris-benzyloxymethoxy-3-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-1-oxo-1,2,3,4-tetrahydro-anthracene-2-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) 0.5 M 9-BBN, 2.) 3 M aq. NaOH, 30percent H₂O₂ / 1.) THF, 23 deg C, 2 h, 2.) 23 deg C, 2 h

2: 90 percent / DMSO, oxalyl chloride / CH₂Cl₂ / 0.17 h / -78 °C

3: 1 M aq. KMnO₄, 1.25 M aq. KH₂PO₄ / 2-methyl-propan-2-ol; dimethylformamide / 0.5 h

4: CH₂Cl₂ / 0.08 h

5: t-BuOK / benzene / 1.5 h / Ambient temperature

With sodium hydroxide; potassium permanganate; potassium dihydrogenphosphate; 9-borabicyclo[3.3.1]nonane dimer; oxalyl dichloride; potassium tert-butylate; dihydrogen peroxide; dimethyl sulfoxide; In dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol; benzene;
DOI:10.1021/ja00190a036